Two new inorganic-organic hybrid compounds templated by SiW12O404- anion with nonlinear ligands

被引：11

作者：

Wang, Xiuli ^{[1
]}

Hu, Hailiang ^{[1
]}

Chen, Baokuan ^{[1
]}

Lin, Hongyan ^{[1
]}

Tian, Aixiang ^{[1
]}

Li, Jin ^{[1
]}

机构：

[1] Bohai Univ, Fac Chem & Chem Engn, Jinzhou 121000, Peoples R China

来源：

SOLID STATE SCIENCES | 2011年 / 13卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Hydrothermal synthesis; Crystal structure; Nonlinear ligands; Electrochemical property; DIMENSIONAL COORDINATION POLYMERS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; BRIDGING LIGAND; CU-II; POLYOXOMETALATE; FRAMEWORKS; CLUSTERS; CHEMISTRY; OXIDES;

D O I：

10.1016/j.solidstatesciences.2010.11.033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new Keggin-type polyoxoanion-templated inorganic-organic hybrids, [Cu(3,4-bpo)(2)(H2O) (SiW12O40)] center dot (3,4-H(2)bpo) center dot 7H(2)O (1), and [Cu(4,4'-Hbpo)(2)(4,4'-bpo)(H2O)(SiW12O40)] center dot 3H(2)O (2) (3,4-bpo = 2-(3-pyridyl)-5-(4-pyridyl)- 1,3,4-oxadiazole, 4,4'-bpo = 2,5-bis(4-pyridyl)-1,3,4-oxadiazole), have been hydrothermally synthesized by changing the terminal N-donor's orientation of the nonlinear ligands. X-ray structural analyses indicate that compound 1 shows a two-dimensional (2D) (4,4) grid sheet. The discrete SiW12O404- anions as templates locate on the square voids of the sheet. Compound 2 exhibits an arm-shaped chain structure. It is believed that the isomeric organic ligands play a key role in the structure control of the self-assembly processes. Furthermore, compound 1 bulk-modified carbon paste electrode (1-CPE) displays good electrocatalytic activity toward the reduction of nitrite. (c) 2010 Elsevier Masson SAS. All rights reserved.

引用

页码：344 / 349

页数：6

共 53 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[2] A new synthesis of symmetrical 2,5-disubstituted 1,3,4-oxadiazoles [J].

Bentiss, F ;

Lagrenée, M .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1999, 36 (04) :1029-1032

[3] Tetrairon and hexairon Hydroxo/Acetato clusters stabilized by multiple polyoxometalate scaffolds. Structures, magnetic properties, and chemistry of a dimer and a trimer [J].

Botar, Bogdan ;

Kogerler, Paul ;

Hill, Craig L. .

INORGANIC CHEMISTRY, 2007, 46 (13) :5398-5403

[4] An unprecedented triply interpenetrated chiral network of 'square-planar' metal centres from the self-assembly of copper(II) nitrate and 1,2-bis(4-pyridyl)ethyne [J].

Carlucci, L ;

Ciani, G ;

Macchi, P ;

Proserpio, DM .

CHEMICAL COMMUNICATIONS, 1998, (17) :1837-1838

[5] A three-dimensional nanoporous flexible network of 'square-planar' copper(II) centres with an unusual topology [J].

Carlucci, L ;

Cozzi, N ;

Ciani, G ;

Moret, M ;

Proserpio, DM ;

Rizzato, S .

CHEMICAL COMMUNICATIONS, 2002, (13) :1354-1355

[6] Solvent-free aerobic oxidation of n-alkane by iron(III)-substituted polyoxotungstates immobilized on SBA-15 [J].

Chen, Lifang ;

Zhu, Kake ;

Bi, Li-Hua ;

Suchopar, Andreas ;

Reicke, Markus ;

Mathys, Georges ;

Jaensch, Helge ;

Kortz, Ulrich ;

Richards, Ryan M. .

INORGANIC CHEMISTRY, 2007, 46 (21) :8457-8459

[7] ELECTROCATALYTIC REDUCTION OF NITRIC-OXIDE TO AMMONIA BY WATER-SOLUBLE IRON PORPHYRIN [J].

CHEN, SM ;

SU, YO .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 280 (01) :189-194

[8] Two-dimensional hydrogen-bonded networks based on bent oxadiazole bridging organic spacers [J].

Cheng, JY ;

Dong, YB ;

Ma, JP ;

Huang, RQ ;

Smith, MD .

INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (01) :6-8

[9] Organic-inorganic hybrid oxides: Structure and magnetic properties of [{Cu(terpy)}2Mo6O17(H2O)(O3PCH2NH2CH2PO3)2] • H2O, a bimetallic oxide constructed from novel {Mo6O17(H2O)(O3PCH2NH2CH2PO3)2}4- clusters [J].

Chuang, Yung-Hsu ;

Liu, Hongxue ;

O'Connor, Charles J. ;

Zubieta, Jon .

INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (10) :1205-1208

[10] Two Novel One-Dimensional α-Keggin-Based Coordination Polymers with Argentophilic {Ag3}3+/{Ag4}4+ Clusters [J].

Dai, Limei ;

You, Wansheng ;

Wang, Enbo ;

Wu, Shuixing ;

Su, Zhongmin ;

Du, Qinghua ;

Zhao, Yi ;

Fang, Yong .

CRYSTAL GROWTH & DESIGN, 2009, 9 (05) :2110-2116

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