Cyclotriphosphazene grafted silica: a novel support for immobilizing the oxo-vanadium Schiff base moieties for hydroxylation of benzene

被引:50
作者
Khatri, Praveen K. [1 ]
Singh, Bhawan [2 ]
Jain, Suman L. [1 ]
Sain, Bir [1 ]
Sinha, Anil K. [2 ]
机构
[1] Indian Inst Petr, Div Chem Sci, Dehra Dun 248005, Uttar Pradesh, India
[2] Indian Inst Petr, Catalyt Convers & Proc Div, Dehra Dun 248005, Uttar Pradesh, India
关键词
HYDROGEN-PEROXIDE; PHENOL; OXIDATION; COMPLEXES;
D O I
10.1039/c0cc01941k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first report on the use of chlorotriphosphazenyl anchored mesoporous silica as a novel support for the immobilization of oxo-vanadium Schiff base moieties is described. The resulting heterogeneous material showed better catalytic activity than homogeneous as well as silica immobilized oxo-vanadium Schiff base for the hydroxylation of benzene with hydrogen peroxide.
引用
收藏
页码:1610 / 1612
页数:3
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