Organic guest molecule induced ultrafast breathing of an epitaxially grown metal-organic framework on a self-assembled monolayer

被引：2

作者：

Rao, Purna Chandra

Mani, Prabu

Son, Younghu

Kim, Jiyun

Yoon, Minyoung ^{[1
]}

机构：

[1] Kyungpook Natl Univ, Dept Chem, Daegu 41566, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 79期

基金：

新加坡国家研究基金会;

关键词：

THIN-FILMS; FABRICATION;

D O I：

10.1039/d1cc03721h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report epitaxially grown new two-dimensional metal-organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules.

引用

页码：10158 / 10161

页数：5

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