Organic guest molecule induced ultrafast breathing of an epitaxially grown metal-organic framework on a self-assembled monolayer

被引：2
|
作者：
Rao, Purna Chandra
Mani, Prabu
Son, Younghu
Kim, Jiyun
Yoon, Minyoung [1 ]
机构：
[1] Kyungpook Natl Univ, Dept Chem, Daegu 41566, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 79期
基金：
新加坡国家研究基金会;
关键词：
THIN-FILMS; FABRICATION;
D O I：
10.1039/d1cc03721h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report epitaxially grown new two-dimensional metal-organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules.
引用
收藏
页码：10158 / 10161
页数：5
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