Characterization of FeCl3 Intercalation Doped CVD Few-Layer Graphene

被引：33

作者：

Liu, Wei ^{[1
]}

Kang, Jiahao ^{[1
]}

Banerjee, Kaustav ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Elect & Comp Engn, Santa Barbara, CA 93106 USA

来源：

IEEE ELECTRON DEVICE LETTERS | 2016年 / 37卷 / 09期

关键词：

Chemical vapor deposition; few-layer graphene; intercalation doping; solar cells; transparent electrodes; BILAYER GRAPHENE; HIGH-QUALITY;

D O I：

10.1109/LED.2016.2597099

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Intercalation doping has been theoretically and experimentally studied on chemical vapor deposition synthesized few-layer graphene. Density functional theory calculations identified FeCl3 as a good dopant to reduce the sheet resistance of few-layer graphene. A simple vapor transfer method is employed to dope graphene. The successful doping is confirmed by the Raman spectra as well as the electrical measurements. After doping, graphene shows p-type conducting behavior and its conductance is significantly enhanced compared with that of undoped graphene. Three-layer graphene exhibited a sheet resistance of 40 Omega/square, while four-layer doped graphene has even smaller sheet resistance of 20 Omega/square, with transmittance >= 90% for both cases, which provide the best combination of sheet resistance and transmittance among all previously reported transparent conductors.

引用

页码：1246 / 1249

页数：4

共 21 条

[1]

Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/NNANO.2010.132, 10.1038/nnano.2010.132]

[2] Large-area functionalized CVD graphene for work function matched transparent electrodes [J].

Bointon, Thomas H. ;

Jones, Gareth F. ;

De Sanctis, Adolfo ;

Hill-Pearce, Ruth ;

Craciun, Monica F. ;

Russo, Saverio .

SCIENTIFIC REPORTS, 2015, 5

[3] Approaching Magnetic Ordering in Graphene Materials by FeCl3 Intercalation [J].

Bointon, Thomas Hardisty ;

Khrapach, Ivan ;

Yakimova, Rositza ;

Shytov, Andrey V. ;

Craciun, Monica F. ;

Russo, Saverio .

NANO LETTERS, 2014, 14 (04) :1751-1755

[4] Are There Fundamental Limitations on the Sheet Resistance and Transmittance of Thin Graphene Films? [J].

De, Sukanta ;

Coleman, Jonathan N. .

ACS NANO, 2010, 4 (05) :2713-2720

[5] Effect of acid treatment on carbon nanotube-based flexible transparent conducting films [J].

Geng, Hong-Zhang ;

Kim, Ki Kang ;

So, Kang Pyo ;

Lee, Young Sil ;

Chang, Youngkyu ;

Lee, Young Hee .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (25) :7758-+

[6] Graphene-Based Electrodes [J].

Huang, Xiao ;

Zeng, Zhiyuan ;

Fan, Zhanxi ;

Liu, Juqing ;

Zhang, Hua .

ADVANCED MATERIALS, 2012, 24 (45) :5979-6004

[7] Graphene and Beyond-Graphene 2D Crystals for Next-Generation Green Electronics [J].

Kang, Jiahao ;

Cao, Wei ;

Xie, Xuejun ;

Sarkar, Deblina ;

Liu, Wei ;

Banerjee, Kaustav .

MICRO- AND NANOTECHNOLOGY SENSORS, SYSTEMS, AND APPLICATIONS VI, 2014, 9083

[8] Prospects of graphene electrodes in photovoltaics [J].

Khatami, Yasin ;

Liu, Wei ;

Kang, Jiahao ;

Banerjee, Kaustav .

NEXT GENERATION (NANO) PHOTONIC AND CELL TECHNOLOGIES FOR SOLAR ENERGY CONVERSION IV, 2013, 8824

[9] Novel Highly Conductive and Transparent Graphene-Based Conductors [J].

Khrapach, Ivan ;

Withers, Freddie ;

Bointon, Thomas H. ;

Polyushkin, Dmitry K. ;

Barnes, William L. ;

Russo, Saverio ;

Craciun, Monica F. .

ADVANCED MATERIALS, 2012, 24 (21) :2844-2849

[10] Large-scale pattern growth of graphene films for stretchable transparent electrodes [J].

Kim, Keun Soo ;

Zhao, Yue ;

Jang, Houk ;

Lee, Sang Yoon ;

Kim, Jong Min ;

Kim, Kwang S. ;

Ahn, Jong-Hyun ;

Kim, Philip ;

Choi, Jae-Young ;

Hong, Byung Hee .

NATURE, 2009, 457 (7230) :706-710

← 1 2 3 →