Experimental study of catalytic degradation of polypropylene by acid-activated clay and performance of Ni as a promoter

被引：7

作者：

Uzair, Muhammad Ali ^{[1
]}

Waqas, Ali ^{[1
]}

Khoja, Asif H. ^{[1
,2
]}

Ahmed, Nisar ^{[3
]}

机构：

[1] Natl Univ Sci & Technol, US Pakistan Ctr Adv Studies Energy USPCAS E, SMME Bldg West Block,Ground Floor Sect H-12, Islamabad 44000, Pakistan

[2] Univ Teknol Malaysia, CREG, Johor Baharu, Malaysia

[3] Natl Ctr Phys, Nano Sci & Catalysis Div, Islamabad, Pakistan

来源：

ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS | 2016年 / 38卷 / 24期

关键词：

Acid-activation; catalytic pyrolysis; hydrocarbons; kaolin; polypropylene;

D O I：

10.1080/15567036.2016.1166163

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Catalytic and thermal cracking of polypropylene was performed in a batch reactor. Effect of hydrochloric acid activation on kaolin clay, effects of catalysts (acid-activated clays), promoter (5 wt% Ni), and cracking temperatures on the liquid oil yield were investigated. Results show optimized liquid yield (71.9%) obtained at 470 degrees C with kaolin clay activated with 3 M HCl. Acid-activated catalysts were analyzed using XRD and the results reveal the reduction in peaks' intensities. Weight loss of polypropylene was investigated by thermogravimetric analysis. FTIR and GCMS techniques were employed to analyze the liquid products.

引用

页码：3618 / 3624

页数：7

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