Mild and efficient CO-mediated eliminative deoxygenation of epoxides catalyzed by supported gold nanoparticles

被引：40

作者：

Ni, Ji ^{[1
]}

He, Lin ^{[1
]}

Liu, Yong-Mei ^{[1
]}

Cao, Yong ^{[1
]}

He, He-Yong ^{[1
]}

Fan, Kang-Nian ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 02期

基金：

中国国家自然科学基金;

关键词：

NITRO-COMPOUNDS; CHEMOSELECTIVE REDUCTION; HYDROGEN SOURCE; OXIDATION; NITROAROMATICS; EPOXIDATION; REAGENTS; OXYGEN; H2O;

D O I：

10.1039/c0cc02783a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Supported gold nanoparticles (NPs), which are well-known epoxidation catalysts, were found to be exceptionally active for the selective deoxygenation of epoxides into alkenes using cheap and easily accessible CO and H2O as the reductant.

引用

页码：812 / 814

页数：3

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