Bimetallic Au-Sn/AC catalysts for acetylene hydrochlorination

被引：60

作者：

Dong, Yanzhao ^{[1
]}

Zhang, Haiyang ^{[1
]}

Li, Wei ^{[2
]}

Sun, Mengxia ^{[2
]}

Guo, Cuili ^{[2
]}

Zhang, Jinli ^{[1
]}

机构：

[1] Tianjin Univ, Key Lab Syst Bioengn MOE, Tianjin 300072, Peoples R China

[2] Tianjin Univ, Key Lab Green Chem Technol MOE, Tianjin 300072, Peoples R China

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2016年 / 35卷

关键词：

Acetylene hydrochlorination; Au-Sn catalyst; Coking deposition; SURFACE ORGANOMETALLIC CHEMISTRY; GOLD CATALYSTS; VINYL-CHLORIDE; PT-SN/AL2O3; CATALYSTS; ALCOHOL OXIDATION; CARBON SUPPORTS; HYDROGEN; DEHYDROGENATION; DEACTIVATION; ISOBUTANE;

D O I：

10.1016/j.jiec.2015.12.031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of Au-Sn/AC catalysts for acetylene hydrochlorination were prepared by an incipient wetness impregnation method and characterized by BET, XPS, TEM, TPR, XRD, ICP-AES and TPD techniques. It is indicated that Au1Sn1/AC catalyst shows the highest activity and stability with the 95% acetylene conversion after 48 h reaction under the conditions of 170 degrees C and an acetylene gas hourly space velocity of 720 h(-1). The Sn additive can make the Au species dispersed well and weaken the occurrence of coke deposition, as well as inhibit the reduction of Au3+ to Au-0, thereby improving the catalytic activity and stability. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：177 / 184

页数：8

共 50 条

[31] Application of SnOx/AC catalyst for the acetylene hydrochlorination
Lu, Ming
Yin, Xue
Wang, Qinqin
Zhang, Xunchao
Zhu, Mingyuan
Dai, Bin
NANO RESEARCH, 2023, 16 (05) : 6577 - 6583
[32] Single-Site Au/Carbon Catalysts with Single-Atom and Au Nanoparticles for Acetylene Hydrochlorination
Lan, Guojun
Ye, Qingfeng
Zhu, Yihan
Tang, Haodong
Han, Wenfeng
Li, Ying
ACS APPLIED NANO MATERIALS, 2020, 3 (03) : 3004 - 3010
[33] Trimetallic Au-Cu-La/AC for Acetylene Hydrochlorination in a Multi-Tubular Fixed Bed Reactor
Wang Lei
Shen Benxian
Zhao Jigang
Wu Chunlei
Bi Xiaotao
IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2020, 39 (01): : 201 - 207
[34] Application of SnOx/AC catalyst for the acetylene hydrochlorination
Ming Lu
Xue Yin
Qinqin Wang
Xunchao Zhang
Mingyuan Zhu
Bin Dai
Nano Research, 2023, 16 (5) : 6577 - 6583
[35] Modifications of the metal and support during the deactivation and regeneration of Au/C catalysts for the hydrochlorination of acetylene
Conte, Marco
Davies, Catherine J.
Morgan, David J.
Davies, Thomas E.
Carley, Albert F.
Johnston, Peter
Hutchings, Graham J.
CATALYSIS SCIENCE & TECHNOLOGY, 2013, 3 (01) : 128 - 134
[36] Development of Au/C catalysts by the microwave-assisted method for the selective hydrochlorination of acetylene
W. Wittanadecha
N. Laosiripojana
A. Ketcong
N. Ningnuek
P. Praserthdam
J. R. Monnier
S. Assabumrungrat
Reaction Kinetics, Mechanisms and Catalysis, 2014, 112 : 189 - 198
[37] Sn-imidazolates supported on boron and nitrogen-doped activated carbon as novel catalysts for acetylene hydrochlorination
Wu, Yibo
Li, Fuxiang
Xue, Jianwei
Lv, Zhiping
CHEMICAL ENGINEERING COMMUNICATIONS, 2020, 207 (09) : 1203 - 1215
[38] Carbon-supported copper organic framework as active catalysts for acetylene hydrochlorination
Wu, Yi-Bo
Ma, Yao
Li, Qing-Bin
Li, Song-Tian
Han, Yong-Jun
Li, Fu-Xiang
CANADIAN JOURNAL OF CHEMISTRY, 2021, 99 (10) : 812 - 816
[39] Improvement of performance of a Au-Cu/AC catalyst using thiol for acetylene hydrochlorination reaction
Hong, Guotai
Tian, Xiaohui
Jiang, Binbo
Liao, Zuwei
Wang, Jingdai
Yang, Yongrong
Zheng, Jie
RSC ADVANCES, 2016, 6 (05): : 3806 - 3814
[40] Highly Efficient Ru@IL/AC To Substitute Mercuric Catalyst for Acetylene Hydrochlorination
Shang, Shanshan
Zhao, Wei
Wang, Yan
Li, Xiaoyan
Zhang, Jinli
Han, You
Li, Wei
ACS CATALYSIS, 2017, 7 (05): : 3510 - 3520

← 1 2 3 4 5 →