Studies on organolanthanide complexes .58. Syntheses of 1,1'-(3-oxa-pentamethylene)dicyclopentadienyl divalent organolanthanides (Ln=Sm, Yb) and X-ray molecular structure of O(CH2CH2C5H4)(2)Yb(DME)

被引：8
作者：
Qian, CT [1 ]
Zhu, CJ [1 ]
Lin, YH [1 ]
Xing, Y [1 ]
机构：
[1] CHINESE ACAD SCI,CHANGCHUN INST APPL CHEM,CHANGCHUN 130022,PEOPLES R CHINA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 507卷 / 1-2期
基金：
中国国家自然科学基金;
关键词：
samarium; ytterbium; cyclopentadienyl; crystal structure; IR spectroscopy; mass spectrometry;
D O I：
10.1016/0022-328X(95)05608-R
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compounds O(CH2CH2C5H4)(2)Ln(THF)(2) [Ln = Sm(1), Yb(2)] were synthesized by the reduction of O(CH2CH2C5H4)(2)LnCl with sodium metal in tetrahydrofuran (THF) at room temperature. Recrystallization of 2 from dimethoxyethane (DME) produced the single-crystal O(CH2CH2C5H4)(2)Yb(DME) (3) whose structure has been determined by an X-ray diffraction study. The crystals are orthorhombic, space group Pcab, with a = 14.168(4), b = 13.541(6), c = 19.314(8) Angstrom, Z = 8, D-calc. = 1.66 g cm(-3).
引用
收藏
页码：41 / 45
页数：5
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