Enriched Catalytic Activity of TiO2 Nanoparticles Supported by Activated Carbon for Noxious Pollutant Elimination

被引:24
|
作者
Rajendran, Suriyaprabha [1 ]
Inwati, Gajendra Kumar [2 ]
Yadav, Virendra Kumar [3 ]
Choudhary, Nisha [1 ]
Solanki, Mitesh B. [4 ]
Abdellattif, Magda H. [5 ]
Yadav, Krishna Kumar [6 ]
Gupta, Neha [7 ]
Islam, Saiful [8 ]
Jeon, Byong-Hun [9 ]
机构
[1] Cent Univ Gujarat, Sch Nanosci, Gandhinagar 302030, Gujarat, India
[2] Rani Durgavati Univ, DP Chaturvedi Coll, Dept Chem, Jabalpur 480661, Madhya Pradesh, India
[3] PP Savani Univ, Sch Sci, Dept Microbiol, Kosamba 394125, Gujarat, India
[4] Step Up Jewels PVT Ltd Khatodara Gate, Surat 395002, Gujarat, India
[5] Taif Univ, Coll Sci, Dept Chem, POB 11099, At Taif 21944, Saudi Arabia
[6] Madhyanchal Profess Univ, Fac Sci & Technol, Bhopal 462044, Madhya Pradesh, India
[7] Bundelkhand Univ, Inst Environm & Dev Studies, Jhansi 284128, Uttar Pradesh, India
[8] King Khalid Univ, Coll Engn, Civil Engn Dept, Abha 61413, Saudi Arabia
[9] Hanyang Univ, Dept Earth Resources & Environm Engn, Seoul 04763, South Korea
关键词
nanocatalysts; activated carbon; effluent; titania; anatase; 2,4-DICHLOROPHENOXYACETIC ACID; REMOVAL; DEGRADATION; PHOTODEGRADATION; PHOTOCATALYSTS; NANOTUBES; NANOCLUSTERS; ENHANCEMENT; ADSORPTION; OZONATION;
D O I
10.3390/nano11112808
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cleaning wastewater has become one of the most serious issues for a number of scientists and researchers in recent years, as water is the most basic need for the daily life of humans. There has been a focus on the removal of noxious pollutants from wastewater effluents by using nanocatalysts owing to their unique physicochemical actions and stability. Herein we manufactured TiO2 nanoparticles supported by activated carbon (AC-TiO2) using a cost-effective sonochemical method. The band structures of the AC-TiO2 and TiO2 were modified from 3.2 to 3.1 eV, thus increasing the catalytic activity. The structural, optical and anatase crystal phase properties, with morphological confirmation, were studied by applying UV-DRS, PL, FESEM, XRD, along with HRTEM, respectively. The specific surface area, calculated by BET analysis, was found to be ~241 m(2)/gm and ~46 m(2)/gm for AC-TiO2 and TiO2. The degradation efficiency of the as-prepared nanocatalysts against the very toxic but rarely studied organic textile dye pollutant RO 84 was investigated and 97% efficiency were found for the AC-TiO2 as compared to pure TiO2, which is a highly appreciated finding in the catalytic dye degradation application domain. Such surface-modified nanocatalysts could be further implemented for the treatment of wastewaters/waste effluents released from chemical industries, laboratories and other sources.
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页数:13
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