Ene-yne cross-metathesis with ruthenium carbene catalysts

被引：66

作者：

Fischmeister, Cedric ^{[1
]}

Bruneau, Christian ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 7卷

关键词：

catalysis; cross-metathesis; enyne; fatty acid esters; ruthenium; RING-CLOSING METATHESIS; INTERMOLECULAR ENYNE METATHESIS; 1,3-DIENE SYNTHESIS; TERMINAL ALKYNES; RAPID ACCESS; ETHYLENE; POLYMERIZATION; DERIVATIVES; COMPLEXES; REACTIVITY;

D O I：

10.3762/bjoc.7.22

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Conjugated 1,3-dienes are important building blocks in organic and polymer chemistry. Enyne metathesis is a powerful catalytic reaction to access such structural domains. Recent advances and developments in ene-yne cross-metathesis (EYCM) leading to various compounds of interest and their intermediates, that can directly be transformed in tandem procedures, are reviewed in this article. In addition, the use of bio-resourced olefinic substrates is presented.

引用

页码：156 / 166

页数：11

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