A broad line NMR and MRI study of water and water transport in Portland cement pastes

被引:94
作者
Bohris, AJ [1 ]
Goerke, U [1 ]
McDonald, PJ [1 ]
Mulheron, M [1 ]
Newling, B [1 ]
Le Page, B [1 ]
机构
[1] Univ Surrey, Sch Phys Sci, Guildford GU2 5XH, Surrey, England
关键词
cement; diffusion; water; stray field imaging (STRAFI); magnetic resonance imaging; relaxation;
D O I
10.1016/S0730-725X(98)00072-1
中图分类号
R8 [特种医学]; R445 [影像诊断学];
学科分类号
1002 ; 100207 ; 1009 ;
摘要
The results of a magnetic resonance spin-spin relaxation analysis and broad-line magnetic resonance imaging (MRI) (gradient-echo and stray-held imaging) study of water and water transport in Portland cement pastes are presented. The effect of varying the cure conditions and the water to cement (w/c) ratio of the sample mix are discussed. The water sorptivity and the concentration dependence of the hydraulic diffusion coefficient are calculated for samples prepared with a 0.5 w/c ratio and, therefore, an open pore structure. In the case of 0.3 w/c ratio samples, little water transport is observed, and a closed pore structure is inferred. (C) 1998 Elsevier Science Inc.
引用
收藏
页码:455 / 461
页数:7
相关论文
共 19 条
[1]  
BLACK S, 1995, J MATER SCI LETT, V14, P1175
[2]   SINGLE-POINT IMAGING OF PARTIALLY DRIED, HYDRATED WHITE PORTLAND-CEMENT [J].
BOGDAN, M ;
BALCOM, BJ ;
BREMNER, TW ;
ARMSTRONG, RL .
JOURNAL OF MAGNETIC RESONANCE SERIES A, 1995, 116 (02) :266-269
[3]   A broad-line nuclear magnetic resonance study of water absorption and transport in fibrous cement roofing tiles [J].
Bohris, AJ ;
Newling, B ;
McDonald, PJ ;
Raoof, A ;
Tran, NL .
JOURNAL OF MATERIALS SCIENCE, 1998, 33 (04) :859-867
[4]  
COTRELL SP, 1990, MEAS SCI TECHNOL, V1, P624
[5]  
Crank J., 1975, MATH DIFFUSION
[6]  
CZEMAN W, 1962, CEMENT CHEM PHYSICS, pCH3
[7]   MOLECULAR DIFFUSION AND NUCLEAR-MAGNETIC-RESONANCE RELAXATION OF WATER IN UNSATURATED POROUS SILICA GLASS [J].
DORAZIO, F ;
BHATTACHARJA, S ;
HALPERIN, WP ;
EGUCHI, K ;
MIZUSAKI, T .
PHYSICAL REVIEW B, 1990, 42 (16) :9810-9818
[8]   NUCLEAR-MAGNETIC-RESONANCE IMAGING OF SIMULATED VOIDS IN CEMENT SLURRIES [J].
FORDHAM, EJ ;
ROBERTS, TPL ;
CARPENTER, TA ;
HALL, LD ;
MAITLAND, GC ;
HALL, C .
AICHE JOURNAL, 1991, 37 (12) :1895-1899
[9]   UNSATURATED WATER-FLOW WITHIN POROUS MATERIALS OBSERVED BY NMR IMAGING [J].
GUMMERSON, RJ ;
HALL, C ;
HOFF, WD ;
HAWKES, R ;
HOLLAND, GN ;
MOORE, WS .
NATURE, 1979, 281 (5726) :56-57
[10]   WATER SORPTIVITY OF MORTARS AND CONCRETES - A REVIEW [J].
HALL, C .
MAGAZINE OF CONCRETE RESEARCH, 1989, 41 (147) :51-61