Resonant neutral particle emission in collisions of electrons with protonated peptides with disulfide bonds at high energies

被引:0
|
作者
Tanabe, Tetsumi [1 ,2 ]
Noda, Koji [2 ]
Miyagi, Satoshi [3 ]
Kurita, Noriyuki [3 ]
Tanaka, Shigenori [4 ]
Setzler, Julia [5 ]
Wenzel, Wolfgang [5 ]
Starikov, Evgeni B. [6 ,7 ,8 ]
Cuniberti, Gianaurelio [6 ,7 ]
机构
[1] High Energy Accelerator Org KEK, Accelerator Lab, Tsukuba, Ibaraki 3050801, Japan
[2] Natl Inst Radiol Sci, Dept Accelerator & Med Phys, Chiba 2638555, Japan
[3] Toyohashi Univ Technol, Dept Knowledge Based Informat Engn, Toyohashi, Aichi 4418580, Japan
[4] Kobe Univ, Grad Sch Syst Informat, Dept Computat Sci, Kobe, Hyogo 6578501, Japan
[5] Karlsruher Inst Technol, Inst Nanotechnol, D-76021 Karlsruhe, Germany
[6] Tech Univ Dresden, Inst Mat Sci, D-01062 Dresden, Germany
[7] POSTECH, Div IT Convergence Engn, Pohang, South Korea
[8] Chalmers Univ Technol, Dept Phys Chem, SE-41296 Gothenburg, Sweden
关键词
HYDROGEN-ATOM ADDUCTS; ELECTROSTATIC STORAGE-RING; CAPTURE DISSOCIATION; ION/ION REACTIONS; AMIDE BOND; ATTACHMENT; RADICALS; PROTEIN; IONS; GENERATION;
D O I
10.1016/j.cplett.2011.01.058
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Electron-ion collisions were studied for various protonated peptide monocations with disulfide bonds, using an electrostatic storage-ring equipped with a merged-electron-beam device. Resonant neutral particle emissions at the energies of 6-7 eV were observed, as well as a rise towards zero-energy, which are typical electron-capture dissociation profiles. The presence of disulfide (S-S) bonds tends to enhance the resonant bump heights. Chemical nature of the amino-acid residues adjacent to cysteines appears to correlate with the bump strength. Molecular-dynamical simulations help clarify the role of molecular vibration modes in the electron-capture dissociation process. (C) 2011 Elsevier B. V. All rights reserved.
引用
收藏
页码:83 / 87
页数:5
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