The role of fly ash microsphere in the microstructure and macroscopic properties of high-strength concrete

被引:179
作者
Wang, Qiang [1 ]
Wang, Dengquan [1 ]
Chen, Honghui [1 ]
机构
[1] Tsinghua Univ, Dept Civil Engn, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
Fly ash microsphere; Silica fume; Hydration; Pore structure; Macroscopic properties; HIGH-PERFORMANCE CONCRETE; DENSIFIED SILICA FUME; AUTOGENOUS SHRINKAGE; MECHANICAL-PROPERTIES; COMPRESSIVE STRENGTH; CEMENT PASTE; PORTLAND-CEMENT; HYDRATION; SLAG; DURABILITY;
D O I
10.1016/j.cemconcomp.2017.07.021
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
This study applied a type of fly ash microsphere (FAM) collected directly from a high-temperature furnace using ceramic dust tubes to high-strength concrete, and with silica fume as a control admixture, investigated the effects of FAM on the hydration and hardening processes of the cementitious materials and the macroscopic properties of the high-strength concrete. Two cement replacement levels (8% and 15%) and two water-to-binder (WEB) ratios (035 and 0.25) were utilized. The results show that FAM has a relatively high level of early activity; SEM images indicate that a significant portion of the FAM reacted at early ages in the cement-FAM hardened paste. Though the early activity of FAM is lower than that of silica fume, the cement-FAM complex binder has similar hydration properties with the cement silica fume complex binder. At 90 d, FAM consumed less Ca(OH)(2) than silica fume and a significant amount of unreacted FAM remained in the hardened pastes. The contributions of FAM to the pore structure of the hardened pastes are lower than those of silica fume at early ages; however, FAM can significantly improve pore structure at late ages, similar to silica fume. In addition, FAM can improve the flowability, late-age strength, and permeability to chloride ions of concrete, while decreasing early-age autogenous shrinkage. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:125 / 137
页数:13
相关论文
共 56 条
[11]   Reaction products of densifted silica fume agglomerates in concrete [J].
Diamond, S ;
Sahu, S ;
Thaulow, N .
CEMENT AND CONCRETE RESEARCH, 2004, 34 (09) :1625-1632
[12]  
Givi A. N., 2008, CONSTR BUILD MATER, V24, P2145
[13]   Strength, permeability and shrinkage cracking of silica fume and metakaolin concretes [J].
Guneyisi, Erhan ;
Gesoglu, Mehmet ;
Karaoglu, Seda ;
Mermerdas, Kasim .
CONSTRUCTION AND BUILDING MATERIALS, 2012, 34 :120-130
[14]   FILLER CEMENT - THE EFFECT OF THE SECONDARY COMPONENT ON THE HYDRATION OF PORTLAND-CEMENT .1. A FINE NONHYDRAULIC FILLER [J].
GUTTERIDGE, WA ;
DALZIEL, JA .
CEMENT AND CONCRETE RESEARCH, 1990, 20 (05) :778-782
[15]   Prediction of compressive strength of fly ash concrete by new apparent activation energy function [J].
Han, SH ;
Kim, JK ;
Park, YD .
CEMENT AND CONCRETE RESEARCH, 2003, 33 (07) :965-971
[16]   Properties of high-strength concrete using a fine fly ash [J].
Haque, MN ;
Kayali, O .
CEMENT AND CONCRETE RESEARCH, 1998, 28 (10) :1445-1452
[17]   Design for durability: The key to improving concrete sustainability [J].
Hooton, R. Doug ;
Bickley, John A. .
CONSTRUCTION AND BUILDING MATERIALS, 2014, 67 :422-430
[18]   Effects of densified silica fume on microstructure and compressive strength of blended cement pastes [J].
Ji, YJ ;
Cahyadi, JH .
CEMENT AND CONCRETE RESEARCH, 2003, 33 (10) :1543-1548
[19]   Autogenous shrinkage of high performance concrete containing mineral admixtures under different curing temperatures [J].
Jiang, Chenhui ;
Yang, Yang ;
Wang, Yong ;
Zhou, Yuenian ;
Ma, Chengchang .
CONSTRUCTION AND BUILDING MATERIALS, 2014, 61 :260-269
[20]   Characteristics of the ultrafine component of fly ash [J].
Jones, M. R. ;
McCarthy, A. ;
Booth, A. P. P. G. .
FUEL, 2006, 85 (16) :2250-2259