Gas-phase hydrogenation of propionitrile catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)

被引：11
作者：
Branco, Joaquim Badalo
Ballivet-Tkatchenko, Danielle
de Matos, Antonio Pires
机构：
[1] Inst Tecnol & Nucl, Dept Quim, P-2686 Sacavem, Portugal
[2] Univ Bourgogne, Fac Sci Mirande, F-21078 Dijon, France
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2007年 / 111卷 / 41期
关键词：
D O I：
10.1021/jp074369n
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrogenation of propionitrile over binary copper-lanthanide intermetallic compounds (LnCu(2), Ln = La, Ce, Pr, Nd) was studied in the gas phase. The results show that the reaction main product is the primary amine, the n-propylamine. To our knowledge, it is the first time that such behavior is reported for copper catalysts.
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页码：15084 / 15088
页数：5
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