Oxidation of styrene catalyzed by ionic manganese porphyrin immobilized in ionic liquid

被引：0

作者：

Liu Ye ^{[1
]}

Zhang Hong-Jiao ^{[1
]}

Wu Hai-Hong ^{[1
]}

Liu Xiu-Li ^{[1
]}

Cai Yue-Qin ^{[1
]}

Lu Yong ^{[1
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai Key LAb Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2007年 / 28卷 / 08期

关键词：

porphyrin; ionic liquid; styrene; catalytic oxidation;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Without the additional involvement of axial ligand and organic solvent, the ionic manganese porphyrin [ Mn (III) (BF4)T(N-Me4-Py) P] [ BF4](4)(1d) immobilized in [ BMIM] BF4 efficiently catalyzed the oxidation of styrene with a good activity(87% conv.) and epoxide selectivity(90%) under mild reaction conditions. The generality of 1d-[ BMIM] BF4 system to the substrates of styrene derivatives with different electronical effects also lead to the pleasing results. The degradation of metalloporphyrin coming from the pi-pi stacking of porphyrin itself and the oxidation destruction was greatly suppressed in this built-up 1d-[ BMIM] BF4 system.

引用

页码：1523 / 1527

页数：5

共 21 条

[1] MECHANISM OF MANGANESE PORPHYRIN-CATALYZED OXIDATION OF ALKENES - ROLE OF MANGANESE(IV) OXO SPECIES
ARASASINGHAM, RD
HE, GX
BRUICE, TC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) : 7985 - 7991
[2] REACTION GAS-CHROMATOGRAPHY WITHOUT SOLVENT FOR IDENTIFICATION OF NANOGRAM QUANTITIES OF NATURAL-PRODUCTS
ATTYGALLE, AB
MORGAN, ED
[J]. ANALYTICAL CHEMISTRY, 1983, 55 (08) : 1379 - 1384
[3] ZEOLITE-ENCAPSULATED AND CLAY-INTERCALATED METAL PORPHYRIN, PHTHALOCYANINE AND SCHIFF-BASE COMPLEXES AS MODELS FOR BIOMIMETIC OXIDATION CATALYSTS - AN OVERVIEW
BEDIOUI, F
[J]. COORDINATION CHEMISTRY REVIEWS, 1995, 144 : 39 - 68
[4] ALKENE EPOXIDATION BY IODOSYLBENZENE CATALYZED BY IRON(III) 5,10,15,20-TETRA(2,6-DICHLOROPHENYL)PORPHYRIN COORDINATED TO PYRIDINE-MODIFIED SILICA
GILMARTIN, C
SMITH, JRL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1995, (02): : 243 - 251
[5] JEANFRANCOIS B, 2000, CHEM COMMUN, P827
[6] Alkene cyclopropanation catalyzed by Halterman iron porphyrin: participation of organic bases as axial ligands
Lai, Tat-Shing
Chan, Fung-Yi
So, Pui-Kin
Ma, Dik-Lung
Wong, Kwok-Yin
Che, Chi-Ming
[J]. DALTON TRANSACTIONS, 2006, (40) : 4845 - 4851
[7] Oxidation of hydrocarbons with iodobenzene diacetate catalyzed by manganese(III) porphyrins in a room temperature ionic liquid
Li, Z
Xia, CG
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 214 (01) : 95 - 101
[8] Oxidation of alkanes catalyzed by manganese(III) porphyrin in an ionic liquid at room temperature
Li, Z
Xia, CG
Xu, CZ
[J]. TETRAHEDRON LETTERS, 2003, 44 (51) : 9229 - 9232
[9] Epoxidation of olefins catalyzed by manganese(III) porphyrin in a room temperature ionic liquid
Li, Z
Xia, CG
[J]. TETRAHEDRON LETTERS, 2003, 44 (10) : 2069 - 2071
[10] Ruthenium meso-tetrakis(2,6-dichlorophenyl)porphyrin complex immobilized in mesoporous MCM-41 as a heterogeneous catalyst for selective alkene epoxidations
Liu, CJ
Yu, WY
Li, SG
Che, CM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (21) : 7364 - 7369

← 1 2 3 →