Diaqua[N, N′-bis(salicylidene) propanediamine(2-)] manganese(III) chloride

被引:2
作者
Hwang, In-Chul
Ha, Kwang [1 ]
机构
[1] Chonnam Natl Univ, Res Inst Catalysis, Sch Appl Chem Engn, Kwangju 500757, South Korea
[2] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词
D O I
10.1107/S1600536807039475
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound (systematic name: diaqua{2,2 '-[propane1,3-diylbis(nitrilomethylidyne)]diphenolato} manganese(III) chloride), [Mn(C17H16N2O2)(H2O)(2)]Cl, consists of an Mn III cation complex and a counter-anion. In the complex, the Mn3+ ion is six-coordinated by the dianion of the tetradentate ligand N,N '-bis(salicylidene)-1,3-diaminopropane and two water molecules in a distorted octahedral geometry. The molecules are assembled through intermolecular O-H center dot center dot center dot Cl and O - H center dot center dot center dot O hydrogen bonds and pi - pi interactions [ the centroid centroid distance is 3.865 angstrom and the dihedral angle between the ring planes is 12.9 degrees] along the a axis.
引用
收藏
页码:M2337 / U831
页数:11
相关论文
共 6 条
[1]  
[Anonymous], 2000, SADABS VERSION 2 03
[2]  
Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565
[3]   SYNTHESIS, STRUCTURE, AND PROPERTIES OF [MN(SALPN)(ETOH)2](CLO4) AND ITS AEROBIC OXIDATION-PRODUCT [MN(SALPN)O]2 [J].
GOHDES, JW ;
ARMSTRONG, WH .
INORGANIC CHEMISTRY, 1992, 31 (03) :368-373
[4]  
Huang DG, 2002, ACTA CHIM SINICA, V60, P1242
[5]  
Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR, P38
[6]   Single-crystal structure validation with the program PLATON [J].
Spek, AL .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :7-13