Synthesis of Poly(3,4-ethylenedioxythiophene) Latexes Using Poly(N-vinylpyrrolidone)-Based Copolymers as Reactive Stabilizers

被引：9
作者：
Mumtaz, Muhammad [1 ,2 ]
Labrugere, Christine [3 ]
Cloutet, Eric [1 ,2 ]
Cramail, Henri [1 ,2 ]
机构：
[1] CNRS, Lab Chim Polymeres Organ, F-33607 Pessac, France
[2] Univ Bordeaux, Lab Chim Polymeres Organ, IPB ENSCBP, F-33607 Pessac, France
[3] CNRS, Inst Chim Mat Condensee Bordeaux, F-33608 Pessac, France
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2010年 / 48卷 / 17期
关键词：
block copolymers; conducting polymers; core-shell polymers; latexes; micelles; poly(3,4-ethylenedioxythiophene); polymerization in dispersed medium; reactive stabilizer; self-assembly; stabilization; LIVING RADICAL POLYMERIZATION; STIMULI-RESPONSIVE VESICLES; SURFACE CHARACTERIZATION; COLLOIDAL DISPERSIONS; POLY(VINYL ALCOHOL); POLYPYRROLE; NANOPARTICLES; ACRYLATES;
D O I：
10.1002/pola.24171
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The synthesis by oxidative polymerization of well-defined poly(3,4-ethylenedioxythiophene) (PEDOT) nano-objects in the presence of modified and unmodified poly(N-vinylpyrrolidone)-based copolymers used as stabilizers in aqueous media is reported. Ammonium persulfate or a mixture of ammonium persulfate with CuCl2 or CuBr2 was used as oxidants. The effects of several parameters such as the molar mass and the concentration of the stabilizer as well as the nature of the oxidants on the size, morphology, and the conductivity of the PEDOT particles have been investigated. The distribution of the reactive moieties along the copolymer stabilizer backbone was shown to be crucial to get well-defined PEDOT nano-objects. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3841-3855, 2010
引用
收藏
页码：3841 / 3855
页数：15
相关论文
共 32 条
  • [1] SYNTHESIS AND CHARACTERIZATION OF AQUEOUS COLLOIDAL DISPERSIONS OF POLY(VINYL ALCOHOL) POLYANILINE PARTICLES
    ARMES, SP
    ALDISSI, M
    AGNEW, S
    GOTTESFELD, S
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 190 : 63 - 74
  • [2] NOVEL COLLOIDAL DISPERSIONS OF POLYANILINE
    ARMES, SP
    ALDISSI, M
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (02) : 88 - 89
  • [3] POLY(1-VINYLIMIDAZOLE-CO-4-AMINOSTYRENE) - STERIC STABILIZER FOR POLYANILINE COLLOIDS
    BAY, RFC
    ARMES, SP
    PICKETT, CJ
    RYDER, KS
    [J]. POLYMER, 1991, 32 (13) : 2456 - 2460
  • [4] Beamon G, 1992, HIGH RESOLUTION XPS
  • [5] Interfacial physicochemical properties of functionalized conducting polypyrrole particles
    Benabderrahmane, S
    Bousalem, S
    Mangeney, C
    Azioune, A
    Vaulay, MJ
    Chehimi, MM
    [J]. POLYMER, 2005, 46 (04) : 1339 - 1346
  • [6] XPS STUDIES OF ENVIRONMENTAL STABILITY OF POLYPYRROLE-POLY(VINYL ALCOHOL) COMPOSITES
    BENSEDDIK, E
    MAKHLOUKI, M
    BERNEDE, JC
    LEFRANT, S
    PRON, A
    [J]. SYNTHETIC METALS, 1995, 72 (03) : 237 - 242
  • [7] Structure of polypeptide-based diblock copolymers in solution:: Stimuli-responsive vesicles and micelles
    Chécot, F
    Brûlet, A
    Oberdisse, J
    Gnanou, Y
    Mondain-Monval, O
    Lecommandoux, S
    [J]. LANGMUIR, 2005, 21 (10) : 4308 - 4315
  • [8] Chécot F, 2002, ANGEW CHEM INT EDIT, V41, P1339, DOI 10.1002/1521-3773(20020415)41:8<1339::AID-ANIE1339>3.0.CO
  • [9] 2-N
  • [10] Synthesis of PEDOT latexes by dispersion polymerization in aqueous media
    Cloutet, Eric
    Mumtaz, Muhammad
    Cramail, Henri
    [J]. MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2009, 29 (02): : 377 - 382
1234