Water as a building block in solid-state acetonitrile-pyrogallol[4]arene assemblies: Structural investigations

被引：46

作者：

Dalgarno, Scott J. ^{[1
]}

Antesberger, Jochen ^{[1
]}

McKinlay, Robert M. ^{[1
]}

Atwood, Jerry L. ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2007年 / 13卷 / 29期

关键词：

calixarenes; host-guest systems; nanocapsules; pyrogallolarenes; self-assembly;

D O I：

10.1002/chem.200700441

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under various conditions, water molecules dramatically affect a number of solid-state C-alkylpyrogallol[4]arene assemblies. In the absence of water, hydrogen-bonded hexameric capsules are formed for the C-butyl, pentyl, hexyl, and heptyl pyrogallol[4]arenes. Introduction of water to acetonitrile solutions containing C-propyl-C-octylpyrogallol [4] arenes resulted in the formation of markedly different bilayer structures and the structural identification of two new dimer-type motifs.

引用

页码：8248 / 8255

页数：8

共 26 条

[1]

Atwood J. L., 2001, J SUPRAMOL CHEM, V1, P131, DOI DOI 10.1016/S1472-7862(02)00003-5

[2] Organization of the interior of molecular capsules by hydrogen bonding [J].