Synthesis crystal growth and properties of the charge transfer complex adduct of 2-nitro aniline with picric acid - An organic non-linear optical material

被引:43
作者
Bharathikannan, R. [2 ]
Chandramohan, A. [3 ]
Kandhaswamy, M. A. [3 ]
Chandrasekaran, J. [2 ]
Renganathan, R. [1 ]
Kandavelu, V. [1 ]
机构
[1] Bharathidasan Univ, Sch Chem, Tiruchirappalli 620024, Tamil Nadu, India
[2] Sri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Phys, Coimbatore 641020, Tamil Nadu, India
[3] Sri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Chem, Coimbatore 641020, Tamil Nadu, India
关键词
charge transfer; solution growth; 2-nitroaniline picric acid adduct; nonlinear optical materials;
D O I
10.1002/crat.200711114
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The organic NLO material 2-nitro aniline and picric acid (2NAP) was synthesized, needle shaped single crystals of dimension 10 x 1 x 0.8 mm(3) were grown by slow evaporation solution growth technique from the saturated solution of the title compound in chloroform at ambient temperature. The material was characterized through elemental analysis, powder XRD, H-1 NMR, C-13 NMR and FTIR techniques. The various planes of reflection have been identified from the XRD powder pattern. The formation of the charge transfer complex was confirmed by UV-VIS spectroscopy. The thermal stability of the crystals was investigated using TG/DTA analyses techniques. The second harmonic generation (SHG) efficiency of the material was estimated using Nd: YAG laser as source. (C) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:683 / 688
页数:6
相关论文
共 14 条
[1]  
[Anonymous], 1995, ORGANIC SPECTROSCOPY
[2]   Optical poling of oligoether acrylate photopolymers doped by stilbene-benzoate derivative chromophores [J].
Kityk, IV ;
Makowska-Janusik, M ;
Gondek, E ;
Krzeminska, L ;
Danel, A ;
Plucinski, KJ ;
Benet, S ;
Sahraoui, B .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2004, 16 (03) :231-239
[3]  
Kuijts R.A., 1989, CHEM PHYS LETT, V156, P209
[4]   A POWDER TECHNIQUE FOR EVALUATION OF NONLINEAR OPTICAL MATERIALS [J].
KURTZ, SK ;
PERRY, TT .
IEEE JOURNAL OF QUANTUM ELECTRONICS, 1968, QE 4 (05) :333-+
[5]   Nonlinear optical properties of some derivatives of stilbene and vinyl cyanide [J].
Li, ZD ;
Wu, KC ;
Su, GB ;
He, YP .
OPTICAL MATERIALS, 2002, 20 (04) :295-299
[6]   L-HISTIDINE TETRAFLUOROBORATE - A SOLUTION-GROWN SEMIORGANIC CRYSTAL FOR NONLINEAR FREQUENCY-CONVERSION [J].
MARCY, HO ;
ROSKER, MT ;
WARREN, LF ;
CUNNINGHAM, PH ;
THOMAS, CA ;
DELOACH, LA ;
VELSKO, SP ;
EBBERS, CA ;
LIAO, JH ;
KANATZIDIS, MG .
OPTICS LETTERS, 1995, 20 (03) :252-254
[7]   Recent development of nonlinear optical borate crystals for UV generation [J].
Mori, Y ;
Yap, YK ;
Kamimura, T ;
Yoshimura, M ;
Sasaki, T .
OPTICAL MATERIALS, 2002, 19 (01) :1-5
[8]   Growth and investigation of new non-linear optical crystals of LAP family [J].
Petrosyan, AM ;
Sukiasyan, RP ;
Karapetyan, HA ;
Terzyan, SS ;
Feigelson, RS .
JOURNAL OF CRYSTAL GROWTH, 2000, 213 (1-2) :103-111
[9]   Synthesis, crystal structures, and quadratic nonlinear optical properties in a series of push pull boronate derivatives [J].
Reyes, H ;
Muñoz, BM ;
Farfán, N ;
Santillan, R ;
Rojas-Lima, S ;
Lacroix, PG ;
Nakatani, K .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (10) :2898-2903
[10]  
ROHATGIMUKHERJE.KK, 2000, FUNDAMENTALS PHOTOCH