Synthesis and crystal structure of metal (M = Ag, Cu) crown ether with N-heterocyclic carbene linkage

被引：24
作者：
Wan, XJ [1 ]
Xu, FB [1 ]
Li, QS [1 ]
Song, HB [1 ]
Zhang, ZZ [1 ]
机构：
[1] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 11期
基金：
中国国家自然科学基金;
关键词：
N-heterocyclic carbene; metallacrown ether; crystal structure;
D O I：
10.1016/j.inoche.2005.08.007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of the carbene precursor 1 and Ag2O yields the Ag(I) metal crown ether 2a. Carbene transmetalation reaction of 2a with CuI gives Cu(I) analogue 2b. The structures of 2a and 2b are determined by X-ray crystallography. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：1053 / 1055
页数：3
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