Electronic Light-Matter Strong Coupling in Nanofluidic Fabry-Perot Cavities

被引：33

作者：

Bahsoun, Hadi ^{[1
,2
]}

Chervy, Thibault ^{[1
,2
]}

Thomas, Anoop ^{[1
,2
]}

Borjesson, Karl ^{[3
]}

Hertzog, Manuel ^{[1
,2
]}

George, Jino ^{[1
,2
]}

Devaux, Eloise ^{[1
,2
]}

Genet, Cyriaque ^{[1
,2
]}

Hutchison, James A. ^{[1
,2
]}

Ebbesen, Thomas W. ^{[1
,2
]}

机构：

[1] Univ Strasbourg, CNRS, ISIS, 8 Allee Gaspard Monge, F-67000 Strasbourg, France

[2] Univ Strasbourg, CNRS, icFRC, 8 Allee Gaspard Monge, F-67000 Strasbourg, France

[3] Univ Gothenburg, Dept Chem & Mol Biol, S-41296 Gothenburg, Sweden

来源：

ACS PHOTONICS | 2018年 / 5卷 / 01期

关键词：

Rabi splitting; Chlorin e6; quantum yield; fluorescence lifetime decay; radiative and nonradiative decay rates; SURFACE-PLASMON POLARITONS; DYNAMICS; PORPHYRIN; MOLECULES; EMISSION; STATES; MODES; WEAK; DYE;

D O I：

10.1021/acsphotonics.7b00679

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Electronic light-matter strong coupling has been limited to solid molecular films due to the challenge of preparing optical cavities with nanoscale dimensions. Here we report a technique to fabricate such Fabry-Perot nanocavities in which solutions can be introduced such that light molecule interactions can be studied at will in the liquid phase. We illustrate the versatility of these cavities by studying the emission properties of Chlorin e6 solutions in both the weak and strong coupling regimes as a function of cavity detuning. Liquid nanocavities will broaden the investigation of strong coupling to many solution-based molecular processes.

引用

页码：225 / 232

页数：8

共 49 条

[21] Modifying Chemical Landscapes by Coupling to Vacuum Fields
Hutchison, James A.
Schwartz, Tal
Genet, Cyriaque
Devaux, Eloise
Ebbesen, Thomas W.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (07) : 1592 - 1596
[22] ARTIFICIAL PHOTOSYNTHESIS .2. INVESTIGATIONS ON THE MECHANISM OF PHOTOSENSITIZATION OF NANOCRYSTALLINE TIO2 SOLAR-CELLS BY CHLOROPHYLL DERIVATIVES
KAY, A
HUMPHRYBAKER, R
GRATZEL, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (03) : 952 - 959
[23] Strong exciton-photon coupling in an organic single crystal microcavity
Kena-Cohen, S.
Davanco, M.
Forrest, S. R.
[J]. PHYSICAL REVIEW LETTERS, 2008, 101 (11)
[24] Non-adiabatic dynamics of molecules in optical cavities
Kowalewski, Markus
Bennett, Kochise
Mukamel, Shaul
[J]. JOURNAL OF CHEMICAL PHYSICS, 2016, 144 (05)
[25] Cavity polaritons with Rydberg blockade and long-range interactions
Litinskaya, Marina
Tignone, Edoardo
Pupillo, Guido
[J]. JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2016, 49 (16)
[26] Coherent Coupling between a Molecular Vibration and Fabry-Perot Optical Cavity to Give Hybridized States in the Strong Coupling Limit
Long, J. P.
Simpkins, B. S.
[J]. ACS PHOTONICS, 2015, 2 (01): : 130 - 136
[27] Strong Magneto-Optical Response of Nonmagnetic Organic Materials Coupled to Plasmonic Nanostructures
Melnikau, Dzmitry
Govyadinov, Alexander A.
Sanchez-Iglesias, Ana
Grzelczak, Marek
Liz-Marzan, Luis M.
Rakovich, Yury P.
[J]. NANO LETTERS, 2017, 17 (03) : 1808 - 1813
[28] Strong light-matter coupling between a molecular vibrational mode in a PMMA film and a low-loss mid-IR microcavity
Muallem, Merav
Palatnik, Alex
Nessim, Gilbert D.
Tischler, Yaakov R.
[J]. ANNALEN DER PHYSIK, 2016, 528 (3-4) : 313 - 320
[29] Coupling between molecular and plasmonic resonances in freestanding dye-gold nanorod hybrid nanostructures
Ni, Weihai
Yang, Zhi
Chen, Huanjun
Li, Li
Wang, Jianfang
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (21) : 6692 - +
[30] Orgiu E, 2015, NAT MATER, V14, P1123, DOI [10.1038/nmat4392, 10.1038/NMAT4392]

← 1 2 3 4 5 →