Electronic Light-Matter Strong Coupling in Nanofluidic Fabry-Perot Cavities

被引：33

作者：

Bahsoun, Hadi ^{[1
,2
]}

Chervy, Thibault ^{[1
,2
]}

Thomas, Anoop ^{[1
,2
]}

Borjesson, Karl ^{[3
]}

Hertzog, Manuel ^{[1
,2
]}

George, Jino ^{[1
,2
]}

Devaux, Eloise ^{[1
,2
]}

Genet, Cyriaque ^{[1
,2
]}

Hutchison, James A. ^{[1
,2
]}

Ebbesen, Thomas W. ^{[1
,2
]}

机构：

[1] Univ Strasbourg, CNRS, ISIS, 8 Allee Gaspard Monge, F-67000 Strasbourg, France

[2] Univ Strasbourg, CNRS, icFRC, 8 Allee Gaspard Monge, F-67000 Strasbourg, France

[3] Univ Gothenburg, Dept Chem & Mol Biol, S-41296 Gothenburg, Sweden

来源：

ACS PHOTONICS | 2018年 / 5卷 / 01期

关键词：

Rabi splitting; Chlorin e6; quantum yield; fluorescence lifetime decay; radiative and nonradiative decay rates; SURFACE-PLASMON POLARITONS; DYNAMICS; PORPHYRIN; MOLECULES; EMISSION; STATES; MODES; WEAK; DYE;

D O I：

10.1021/acsphotonics.7b00679

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Electronic light-matter strong coupling has been limited to solid molecular films due to the challenge of preparing optical cavities with nanoscale dimensions. Here we report a technique to fabricate such Fabry-Perot nanocavities in which solutions can be introduced such that light molecule interactions can be studied at will in the liquid phase. We illustrate the versatility of these cavities by studying the emission properties of Chlorin e6 solutions in both the weak and strong coupling regimes as a function of cavity detuning. Liquid nanocavities will broaden the investigation of strong coupling to many solution-based molecular processes.

引用

页码：225 / 232

页数：8

共 49 条

[1] Dynamics of Strongly Coupled Modes between Surface Plasmon Polaritons and Photoactive Molecules: The Effect of the Stokes Shift
Baieva, Svitlana
Hakamaa, Ossi
Groenhof, Gerrit
Heikkila, Tero T.
Toppari, Jussi
[J]. ACS PHOTONICS, 2017, 4 (01): : 28 - 37
[2] Polariton-Induced Enhanced Emission from an Organic Dye under the Strong Coupling Regime
Ballarini, Dario
De Giorgi, Milena
Gambino, Salvatore
Lerario, Giovanni
Mazzeo, Marco
Genco, Armando
Accorsi, Gianluca
Giansante, Carlo
Colella, Silvia
D'Agostino, Stefania
Cazzato, Paolo
Sanvitto, Daniele
Gigli, Giuseppe
[J]. ADVANCED OPTICAL MATERIALS, 2014, 2 (11): : 1076 - 1081
[3] Strong Coupling between Plasmons and Organic Semiconductors
Bellessa, Joel
Symonds, Clementine
Laverdant, Julien
Benoit, Jean-Michel
Plenet, Jean Claude
Vignoli, Stephane
[J]. ELECTRONICS, 2014, 3 (02): : 303 - 313
[4] Active Control of the Strong Coupling Regime between Porphyrin Excitons and Surface Plasmon Polaritons
Berrier, Audrey
Cools, Ruud
Arnold, Christophe
Offermans, Peter
Crego-Calama, Mercedes
Brongersma, Sywert H.
Rivas, Jaime Gomez
[J]. ACS NANO, 2011, 5 (08) : 6226 - 6232
[5] Vibrational Strong Coupling of Organometallic Complexes
Casey, Shaelyn R.
Sparks, Justin R.
[J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (49) : 28138 - 28143
[6] High-Efficiency Second-Harmonic Generation from Hybrid Light Matter States
Chervy, Thibault
Xu, Jialiang
Duan, Yulong
Wang, Chunliang
Mager, Loic
Frerejean, Maurice
Munninghoff, Joris A. W.
Tinnemans, Paul
Hutchison, James A.
Genet, Cyriaque
Rowan, Alan E.
Rasing, Theo
Ebbesen, Thomas W.
[J]. NANO LETTERS, 2016, 16 (12) : 7352 - 7356
[7] Daskalakis KS, 2014, NAT MATER, V13, P272, DOI [10.1038/NMAT3874, 10.1038/nmat3874]
[8] Modified relaxation dynamics and coherent energy exchange in coupled vibration-cavity polaritons
Dunkelberger, A. D.
Spann, B. T.
Fears, K. P.
Simpkins, B. S.
Owrutsky, J. C.
[J]. NATURE COMMUNICATIONS, 2016, 7
[9] Hybrid Light-Matter States in a Molecular and Material Science Perspective
Ebbesen, Thomas W.
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (11) : 2403 - 2412
[10] CONTACT ADHESION OF THIN GOLD-FILMS ON ELASTOMERIC SUPPORTS - COLD WELDING UNDER AMBIENT CONDITIONS
FERGUSON, GS
CHAUDHURY, MK
SIGAL, GB
WHITESIDES, GM
[J]. SCIENCE, 1991, 253 (5021) : 776 - 778

← 1 2 3 4 5 →