Metal-free dehydrosulfurization of thioamides to nitriles under visible light

被引：12
|
作者：
Xu, Tianxiao [1 ]
Cao, Tianpeng [1 ]
Feng, Qingyuan [2 ]
Huang, Shenlin [2 ]
Liao, Saihu [1 ]
机构：
[1] Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, 2 Xueyuan Rd, Fuzhou 350116, Peoples R China
[2] Nanjing Forestry Univ, Jiangsu Prov Key Lab Chem & Utilizat Agroforest B, Coll Chem Engn, Nanjing 210037, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 38期
关键词：
C-H CYANATION; PHOTOREDOX CATALYSIS; FACILE SYNTHESIS; HYDROCYANATION;
D O I：
10.1039/d0cc01380c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A visible light-mediated, metal-free dehydrosulfurization reaction of thioamides to nitriles is described. This reaction features high yields, mild reaction conditions, and the use of a cheap organic dye as the photoredox catalyst and air as the oxidant.
引用
收藏
页码：5151 / 5153
页数：3
相关论文
共 50 条
  • [41] Metal-Free, Site-Selective C-H Fluorination of Heteroarenes Under Visible Light
    Huang, Cheng
    You, Chang-Ming
    Qin, Yu-Shu
    Ci, Rui-Nan
    Xiao, Peng
    Tang, Sheng
    Liu, Bin
    Wei, Zhenhong
    Wu, Li-Zhu
    Cai, Hu
    CCS CHEMISTRY, 2024, 6 (07): : 1681 - 1688
  • [42] Metal-free disinfection effects induced by graphitic carbon nitride polymers under visible light illumination
    Huang, Jianhui
    Ho, Wingkei
    Wang, Xinchen
    CHEMICAL COMMUNICATIONS, 2014, 50 (33) : 4338 - 4340
  • [43] Efficiency and stability of metal-free carbon nitride in the photocatalytic ozonation of oxamic acid under visible light
    Orge, Carla A.
    Sampaio, Maria J.
    Faria, Joaquim L.
    Pereira, M. Fernando R.
    Silva, Claudia G.
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2020, 8 (05):
  • [44] Visible-Light Photoredox-Catalyzed Thioacetalization of Aldehydes Under Metal-Free and Solvent-Free Conditions
    Du, Kai
    Wang, Shao-Chien
    Basha, R. Sidick
    Lee, Chin-Fa
    ADVANCED SYNTHESIS & CATALYSIS, 2019, 361 (07) : 1597 - 1605
  • [45] Visible-Light-Promoted Metal-Free Synthesis of (Hetero)Aromatic Nitriles from C(sp3)-H Bonds**
    Murugesan, Kathiravan
    Donabauer, Karsten
    Konig, Burkhard
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (05) : 2439 - 2445
  • [46] Catalytic, Metal-Free Oxidation of Primary Amines to Nitriles
    Lambert, Kyle M.
    Eldirany, Sherif A.
    Bobbitt, James M.
    Bailey, William F.
    ORGANIC SYNTHESES, 2018, 95 : 60 - +
  • [47] Metal-free, light assisted integrated CO 2 reduction coupled with selective oxidation of alcohols under visible light irradiation
    Saini, Nitish
    Malik, Anil
    Abraham, Moses
    Jain, Suman L.
    MOLECULAR CATALYSIS, 2024, 564
  • [48] Siloxene: An advanced metal-free catalyst for efficient photocatalytic reduction of aqueous Cr(VI) under visible light
    Li, Minzhang
    Ramachandran, Rajendran
    Sakthivel, Thangavel
    Wang, Fei
    Xu, Zong-Xiang
    CHEMICAL ENGINEERING JOURNAL, 2021, 421
  • [49] Amoxicillin photodegradation under visible light catalyzed by metal-free carbon nitride: An investigation of the influence of the structural defects
    Silva, Ingrid F.
    Teixeira, Ivo F.
    Rios, Regiane D. F.
    do Nascimento, Gustavo M.
    Binatti, Ildefonso
    Victoriae, Henrique F. V.
    Krambrock, Klaus
    Cury, Luiz A.
    Teixeira, Ana Paula C.
    Stumpf, Humberto O.
    JOURNAL OF HAZARDOUS MATERIALS, 2021, 401
  • [50] Photoactive and metal-free polyamide-based polymers for water and wastewater treatment under visible light irradiation
    Shen, Junjie
    Steinbach, Roman
    Tobin, John M.
    Nakata, Mayumi Mouro
    Bower, Matthew
    McCoustra, Martin R. S.
    Bridle, Helen
    Arrighi, Valeria
    Vilela, Filipe
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 193 : 226 - 233
12345