Metal-free dehydrosulfurization of thioamides to nitriles under visible light

被引：12
|
作者：
Xu, Tianxiao [1 ]
Cao, Tianpeng [1 ]
Feng, Qingyuan [2 ]
Huang, Shenlin [2 ]
Liao, Saihu [1 ]
机构：
[1] Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, 2 Xueyuan Rd, Fuzhou 350116, Peoples R China
[2] Nanjing Forestry Univ, Jiangsu Prov Key Lab Chem & Utilizat Agroforest B, Coll Chem Engn, Nanjing 210037, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 38期
关键词：
C-H CYANATION; PHOTOREDOX CATALYSIS; FACILE SYNTHESIS; HYDROCYANATION;
D O I：
10.1039/d0cc01380c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A visible light-mediated, metal-free dehydrosulfurization reaction of thioamides to nitriles is described. This reaction features high yields, mild reaction conditions, and the use of a cheap organic dye as the photoredox catalyst and air as the oxidant.
引用
收藏
页码：5151 / 5153
页数：3
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