Eco-friendly modification of a regenerated cellulose based film by silicon, carbon and N-doped carbon quantum dots

被引:42
作者
Cuevas, A. [1 ]
Campos, B. B. [2 ]
Romero, R. [1 ]
Algarra, M. [3 ]
Vazquez, Ma I. [4 ]
Benavente, J. [4 ]
机构
[1] Univ Malaga, Ctr Supercomp & Bioinnovac, Unidad Nanotecnol, E-29071 Malaga, Spain
[2] Univ Porto, Dept Quim, Ctr Invest Quim, Fac Ciencias, P-4169007 Porto, Portugal
[3] Univ Madeira, CQM, Campus Penteada, P-9020105 Funchal, Portugal
[4] Univ Malaga, Grp Caracterizac Electrocinet Membranas & Interfa, Dept Fis Aplicada 1, Fac Ciencias, E-29071 Malaga, Spain
关键词
Cellulosic films; Carbon nanodots; Spectroscopy ellipsometry; Transmittance; CARBOXYMETHYL CELLULOSE; BACTERIAL CELLULOSE; DRUG-DELIVERY; MEMBRANE; NANOPARTICLES; ELLIPSOMETRY; NANOCRYSTALS; INCLUSION; DENDRIMER; CHEMISTRY;
D O I
10.1016/j.carbpol.2018.10.074
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Modification of a regenerated cellulose thin film by inclusion of different non-toxic nanodots (silicon-dots (SiDs), carbon-dots (CDs)) or nitrogen-doped carbon dots (N-CDs)) by aqueous nanodots solution immersion was performed. Nanodots presence into the cellulosic structure was evidenced by confocal microscopy images at different depth and changes in film mechanical, electrical and optical parameters. Our results reveal that the inclusion of the different nanodots in the cellulosic support increases, indifferent percentages, the mechanical resistance and electrical conductivity of modified films, but they hardly affect light transmittance. Particularly, modification with N-CDs largely favored film conductivity due to the presence of the higher number of charged functional groups (C-NH2 and O=C-NH2) groups) on N-CDs surface, allowin gus the attainment of a flexible, fluorescent and transparent high conductive eco-friendly film. In fact, the non-toxic character of both support-film and nanodots, endorses the use of these new nano-engineering films in biomedical applications.
引用
收藏
页码:238 / 244
页数:7
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