(Acetylacetonato-κ2O,O′)aqua[salicyl-aldehyde nicotinoylhydrazonato(2-)-κ3O,N,O′]manganese(III)

被引:3
|
作者
Wang, Zeng-You [1 ]
Liu, Shi-Xiong [1 ]
Fu, Zhong-Wu [1 ]
机构
[1] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536807060734
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The MnIII atom in the title complex, [Mn(C13H9N3O2)(C5H7O2)(H2O) ], is coordinated by three donors from a dianionic ligand, salicylaldehyde nicotylhydrazone, two O atoms from an acetyl-acetonate anion and a water mol-ecule in a distorted octa-hedral geometry. There is an extended two-dimensional supra-molecular motif resulting from O - H⋯N hydrogen bonds between the coordinated water mol-ecule and a hydrazine N or pyridine N atom, and from C - H⋯O hydrogen bonds between a CH group and the phenolate O atom. © 2008 International Union of Crystallography.
引用
收藏
页码:M371 / U869
页数:13
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