Catalytic Alkylation Routes via Carbonium-Ion-Like Transition States on Acidic Zeolites

被引:11
作者
Gounder, Rajamani [1 ]
Iglesia, Enrique [1 ,2 ]
机构
[1] Univ Calif Berkeley, Dept Chem Engn, Berkeley, CA 94720 USA
[2] EO Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA
关键词
alkylation; Bronsted acid; carbonium ion; cracking; zeolites; PROPANE AROMATIZATION; PHOSPHOTUNGSTIC ACID; LOCAL-STRUCTURE; CONVERSION; CRACKING; METHANE; CHEMISTRY; MECHANISM; ETHYLENE; ALKENES;
D O I
10.1002/cctc.201100051
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
[No abstract available]
引用
收藏
页码:1134 / 1138
页数:5
相关论文
共 31 条
  • [11] Catalytic hydrogenation of alkenes on acidic zeolites: Mechanistic connections to monomolecular alkane dehydrogenation reactions
    Gounder, Rajamani
    Iglesia, Enrique
    [J]. JOURNAL OF CATALYSIS, 2011, 277 (01) : 36 - 45
  • [12] Effects of Partial Confinement on the Specificity of Monomolecular Alkane Reactions for Acid Sites in Side Pockets of Mordenite
    Gounder, Rajamani
    Iglesia, Enrique
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (04) : 808 - 811
  • [13] Catalytic Consequences of Spatial Constraints and Acid Site Location for Monomolecular Alkane Activation on Zeolites
    Gounder, Rajamani
    Iglesia, Enrique
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) : 1958 - 1971
  • [14] Haag W.O., 1984, P 8 INT C CATALYSIS, V2, P305
  • [15] Propene production from ethene and methane using silver- and proton-exchanged zeolite catalysts
    Inazu, Koji
    Koyama, Toru
    Miyaji, Akimitsu
    Baba, Toshihide
    [J]. JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 2008, 51 (04) : 205 - 216
  • [16] A quantum chemical study of tertiary carbenium ions in acid catalyzed hydrocarbon conversions over phosphotungstic acid
    Janik, Michael J.
    Davis, Robert J.
    Neurock, Matthew
    [J]. CATALYSIS TODAY, 2006, 116 (02) : 90 - 98
  • [17] A density functional theory study of the alkylation of isobutane with butene over phosphotungstic acid
    Janik, Michael J.
    Davis, Robert J.
    Neurock, Matthew
    [J]. JOURNAL OF CATALYSIS, 2006, 244 (01) : 65 - 77
  • [18] DFT-based reaction pathway analysis of hexadiene cyclization via carbenium ion intermediates: Mechanistic study of light alkane aromatization catalysis
    Joshi, YV
    Bhan, A
    Thomson, KT
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (03) : 971 - 980
  • [19] The Haag-Dessau mechanism of protolytic cracking of alkanes
    Kotrel, S
    Knözinger, H
    Gates, BC
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2000, 35-6 : 11 - 20
  • [20] Key role of the pore volume of zeolite for selective production of propylene from olefins
    Koyama, To-ru
    Hayashi, Yoshihiro
    Horie, Hironori
    Kawauchi, Susumu
    Matsumoto, Akihiko
    Iwase, Yasuyoshi
    Sakamoto, Yasuharu
    Miyaji, Akimitsu
    Motokura, Ken
    Baba, Toshihide
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (11) : 2541 - 2554