Palladium-catalysed telomerization of butadiene with aldoses:: A convenient route to non-ionic surfactants based on controlled reactions

被引：20

作者：

Bessmertnykh, A ^{[1
]}

Hénin, F ^{[1
]}

Muzart, J ^{[1
]}

机构：

[1] Univ Reims, CNRS, Unite Mixte Rech React Select & Applicat, F-51687 Reims, France

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2005年 / 238卷 / 1-2期

关键词：

telomerization; palladium; aldoses; mono and di-octadienyl glycosides;

D O I：

10.1016/j.molcata.2005.05.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Palladium-catalysed telomerization of butadiene with aldoses in an organic medium can be directed towards the formation of mono- or di-octadienyl ethers. The relative reactant ratios and the amounts of dissolved gaseous butadiene have been defined as the crucial parameters to this purpose. The resulting octadienyl ethers could be hydrogenated, leading to the corresponding saturated non-ionic surfactants. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：199 / 206

页数：8

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