Transition metal complexes with 2-(N-tosylamino)benzaldehyde 1-phthalazinylhydrazone

被引：19

作者：

Popov, L. D. ^{[1
]}

Shcherbakov, I. N. ^{[1
]}

Levchenkov, S. I. ^{[2
]}

Tupolova, Yu. P. ^{[1
]}

Burlov, A. S. ^{[1
]}

Aleksandrov, G. G. ^{[3
]}

Lukov, V. V. ^{[1
]}

Kogan, V. A. ^{[1
]}

机构：

[1] So Fed Univ, Rostov Na Donu, Russia

[2] Russian Acad Sci, So Sci Ctr, Rostov Na Donu, Russia

[3] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 37卷 / 07期

关键词：

MAGNETIC EXCHANGE; COPPER(II); CRYSTAL; HYDRAZONES; CHEMISTRY; TRENDS;

D O I：

10.1134/S1070328411060078

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2-(N-Tosylamino)benzaldehyde 1-phthalazinylhydrazone (H2L) and its complexes with Cu(II), Ni(II), and Mn(II) were obtained. The acid-basic properties of the hydrazone were studied using potentiometry and spectrophotometry. The experimental data were compared with the results of quantum-chemical DFT calculations. The structure of the binuclear complex [Cu2L2] was determined using X-ray diffraction. The broken symmetry approach was used to calculate the exchange coupling constant of the copper ions.

引用

页码：483 / 491

页数：9

共 41 条

[1] ABRAHAM F, 1991, DALTON T, P1443
[2] Coordination motifs in modern supramolecular chemistry
Alexeev, Yu. E.
Kharisov, B. I.
Hernandez Garcia, T. C.
Garnovskii, A. D.
[J]. COORDINATION CHEMISTRY REVIEWS, 2010, 254 (7-8) : 794 - 831
[3] [Anonymous], 1994, Sovremennaya magnetokhimiya (Modern Magnetochemistry)
[4] Treatment of electronic excitations within the adiabatic approximation of time dependent density functional theory
Bauernschmitt, R
Ahlrichs, R
[J]. CHEMICAL PHYSICS LETTERS, 1996, 256 (4-5) : 454 - 464
[5] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE
BECKE, AD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) : 5648 - 5652
[6] DENSITY-FUNCTIONAL EXCHANGE-ENERGY APPROXIMATION WITH CORRECT ASYMPTOTIC-BEHAVIOR
BECKE, AD
[J]. PHYSICAL REVIEW A, 1988, 38 (06): : 3098 - 3100
[7] Bleaney B., 1952, P R SOC LONDON A, P214
[8] BURLOV AS, 2008, ZH NEORG KHIM, V53, P1677
[9] Frisch M., 2004, GAUSSIAN 03 REVISION, DOI DOI 10.1016/J.MOLSTRUC.2017.03.014
[10] Quantum tunneling of magnetization and related phenomena in molecular materials
Gatteschi, D
Sessoli, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (03) : 268 - 297

← 1 2 3 4 5 →