Formation and in situ characterization of the first dihydrogen aqua complex:: [Ru(H2O)5(H2)]2+

被引：32

作者：

Aebischer, N ^{[1
]}

Frey, U ^{[1
]}

Merbach, AE ^{[1
]}

机构：

[1] Univ Lausanne, BCH Dorigny, Inst Chim Minerale & Analyt, CH-1015 Lausanne, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 21期

关键词：

D O I：

10.1039/a805579c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The product of the reaction between [Ru(H2O)(6)](2+) and pressurized H-2 in water is [Ru(H2O)(5)(H-2)](2+) whose nature was unambiguously demonstrated by H-1 and O-17 NMR and which is the first characterized dihydrogen aqua complex.

引用

页码：2303 / 2304

页数：2

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