Microwave-assisted nickel(II) acetylacetonate-catalyzed arylation of aldehydes with arylboronic acids

被引：18
作者：
Chen, Wen [1 ,2 ,3 ]
Baghbanzadeh, Mostafa [1 ,2 ]
Kappe, C. Oliver [1 ,2 ]
机构：
[1] Karl Franzens Univ Graz, Christian Doppler Lab Microwave Chem, A-8010 Graz, Austria
[2] Karl Franzens Univ Graz, Inst Chem, A-8010 Graz, Austria
[3] E China Univ Sci & Technol, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 14期
关键词：
Arylation; 1,2-Addition; Boronic acid; Catalysis. Microwave-assisted synthesis; Nickel; ADDITION-REACTIONS; DIRHODIUM(II) COMPLEXES; AROMATIC-ALDEHYDES; SILICON-CARBIDE; 1,2-ADDITION; CHEMISTRY; LIGANDS; KETONES; METAL;
D O I：
10.1016/j.tetlet.2011.01.147
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Applying sealed vessel microwave heating at 180 degrees C in toluene the arylation of aromatic and aliphatic aldehydes with arylboronic acids using 1-2 mol % of Ni(acac)(2) as a catalyst can be performed efficiently within 10-30 min providing the desired diarylmethanols or benzyl alcohols in good yields. (c) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1677 / 1679
页数：3
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