Microwave-assisted nickel(II) acetylacetonate-catalyzed arylation of aldehydes with arylboronic acids

被引：18

作者：

Chen, Wen ^{[1
,2
,3
]}

Baghbanzadeh, Mostafa ^{[1
,2
]}

Kappe, C. Oliver ^{[1
,2
]}

机构：

[1] Karl Franzens Univ Graz, Christian Doppler Lab Microwave Chem, A-8010 Graz, Austria

[2] Karl Franzens Univ Graz, Inst Chem, A-8010 Graz, Austria

[3] E China Univ Sci & Technol, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 14期

关键词：

Arylation; 1,2-Addition; Boronic acid; Catalysis. Microwave-assisted synthesis; Nickel; ADDITION-REACTIONS; DIRHODIUM(II) COMPLEXES; AROMATIC-ALDEHYDES; SILICON-CARBIDE; 1,2-ADDITION; CHEMISTRY; LIGANDS; KETONES; METAL;

D O I：

10.1016/j.tetlet.2011.01.147

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Applying sealed vessel microwave heating at 180 degrees C in toluene the arylation of aromatic and aliphatic aldehydes with arylboronic acids using 1-2 mol % of Ni(acac)(2) as a catalyst can be performed efficiently within 10-30 min providing the desired diarylmethanols or benzyl alcohols in good yields. (c) 2011 Elsevier Ltd. All rights reserved.

引用

页码：1677 / 1679

页数：3

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