A concave-bound CpFe complex of sumanene as a metal in a π bowl

被引：85

作者：

Amaya, Toru ^{[1
]}

Sakane, Hiroyuki ^{[1
]}

Hirao, Toshikazu ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 44期

关键词：

arene ligands; coordination modes; ferrocene; fullerene derivatives; structure elucidation;

D O I：

10.1002/anie.200702826

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Dished up: The selective synthesis of a concave-bound iron complex was achieved by ligand exchange of a cyclopentadienyl ring of ferrocene with a fullerene-fragment π bowl, sumanene (see picture). The concave π surface serves as an η6 ligand. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8376 / 8379

页数：4

共 43 条

[1] CAPILLARITY-INDUCED FILLING OF CARBON NANOTUBES [J].

AJAYAN, PM ;

IIJIMA, S .

NATURE, 1993, 361 (6410) :333-334

[2] η6-corannulene buckybowl complexes of iridium, including ring-to-ring migration [J].

Alvarez, CM ;

Angelici, RJ ;

Sygula, A ;

Sygula, R ;

Rabideau, PW .

ORGANOMETALLICS, 2003, 22 (04) :624-626

[3] Synthesis and characterization of π-extended bowl-shaped π-conjugated molecules [J].

Amaya, Toru ;

Mori, Koichi ;

Wu, Hsyueh-Liang ;

Ishida, Satoshi ;

Nakamura, Jun-ichi ;

Murata, Kazuhiko ;

Hirao, Toshikazu .

CHEMICAL COMMUNICATIONS, 2007, (19) :1902-1904

[4]

[Anonymous], ANGEW CHEM

[5]

[Anonymous], 2006, ANGEW CHEM, V118, P7366

[6] Laser plasma production of metal-corannulene ion-molecule complexes [J].

Ayers, TM ;

Westlake, BC ;

Preda, DV ;

Scott, LT ;

Duncan, MA .

ORGANOMETALLICS, 2005, 24 (19) :4573-4578

[7] Reactions of transition metal complexes with fullerenes (C60, C70, etc.) and related materials [J].

Balch, AL ;

Olmstead, MM .

CHEMICAL REVIEWS, 1998, 98 (06) :2123-2165

[8] Fullerometallic ion chemistry:: Reactions of C60Fe+ and C20H10Fe+ in the gas phase [J].

Caraiman, D ;

Koyanagi, GK ;

Scott, LT ;

Preda, DV ;

Bohm, DK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (35) :8573-8582

[9] FULLERENES WITH METALS INSIDE [J].

CHAI, Y ;

GUO, T ;

JIN, CM ;

HAUFLER, RE ;

CHIBANTE, LPF ;

FURE, J ;

WANG, LH ;

ALFORD, JM ;

SMALLEY, RE .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (20) :7564-7568

[10] Binding of transition-metal ions to curved π surfaces:: Corannulene and coronene [J].

Dunbar, RC .

JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (42) :9809-9819

← 1 2 3 4 5 →