Selective oxidations of sulfides to sulfoxides using immobilised cerium alkyl phosphonate

被引:25
作者
Al-Hashimi, M [1 ]
Roy, G [1 ]
Sullivan, AC [1 ]
Wilson, JRH [1 ]
机构
[1] Queen Mary Univ London, Dept Chem, London E1 4NS, England
关键词
sulfide; sulfoxide; oxidation; cerium; phosphonate; silica; immobilised reagents;
D O I
10.1016/j.tetlet.2005.04.079
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A range of sulfides can be selectively oxidised to the corresponding sulfoxides in good yields using catalytic quantities of immobilised cerium alkyl phosphonate and either sodium brornate or tert-butyl hydroperoxide as oxidants. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4365 / 4368
页数:4
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