Selective oxidations of sulfides to sulfoxides using immobilised cerium alkyl phosphonate

被引:25
作者
Al-Hashimi, M [1 ]
Roy, G [1 ]
Sullivan, AC [1 ]
Wilson, JRH [1 ]
机构
[1] Queen Mary Univ London, Dept Chem, London E1 4NS, England
关键词
sulfide; sulfoxide; oxidation; cerium; phosphonate; silica; immobilised reagents;
D O I
10.1016/j.tetlet.2005.04.079
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A range of sulfides can be selectively oxidised to the corresponding sulfoxides in good yields using catalytic quantities of immobilised cerium alkyl phosphonate and either sodium brornate or tert-butyl hydroperoxide as oxidants. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4365 / 4368
页数:4
相关论文
共 17 条
  • [1] Oxidation of alcohols using cerium(IV) alkyl phosphonate modified silica
    Al-Haq, N
    Sullivan, AC
    Wilson, JRH
    [J]. TETRAHEDRON LETTERS, 2003, 44 (04) : 769 - 771
  • [2] Porous silica and polysilsesquioxane with covalently linked phosphonates and phosphonic acids
    Aliev, A
    Ou, DL
    Ormsby, B
    Sullivan, AC
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (12) : 2758 - 2764
  • [3] SURFACE-MEDIATED REACTIONS .5. OXIDATION OF SULFIDES, SULFOXIDES, AND ALKENES WITH TERT-BUTYL HYDROPEROXIDE
    BRETON, GW
    FIELDS, JD
    KROPP, PJ
    [J]. TETRAHEDRON LETTERS, 1995, 36 (22) : 3825 - 3828
  • [4] Tungstate-exchanged Mg-Al-LDH catalyst: an eco-compatible route for the oxidation of sulfides in aqueous medium
    Choudary, BM
    Bharathi, B
    Reddy, CV
    Kantam, ML
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2002, (18): : 2069 - 2074
  • [5] Large pore Ti-zeolites and mesoporous Ti-silicalites as catalysts for selective oxidation of organic sulfides
    Corma, A
    Iglesias, M
    Sanchez, F
    [J]. CATALYSIS LETTERS, 1996, 39 (3-4) : 153 - 156
  • [6] A mild, efficient and selective oxidation of sulfides to sulfoxides
    Fraile, JM
    García, JI
    Lázaro, B
    Mayoral, JA
    [J]. CHEMICAL COMMUNICATIONS, 1998, (17) : 1807 - 1808
  • [7] Selective oxidations of allylic alcohols using vanadyl and cobalt(II) alkyl phosphonate modified silicas
    Jurado-Gonzalez, M
    Sullivan, AC
    Wilson, JRH
    [J]. TETRAHEDRON LETTERS, 2004, 45 (23) : 4465 - 4468
  • [8] Allylic and benzylic oxidation using cobalt(II) alkyl phosphonate modified silica
    Jurado-Gonzalez, M
    Sullivan, AC
    Wilson, JRH
    [J]. TETRAHEDRON LETTERS, 2003, 44 (22) : 4283 - 4286
  • [9] Synthesis, characterisation and catalytic activity of porous vanadyl phosphonate-modified silicas
    Jurado-Gonzalez, M
    Ou, DL
    Sullivan, AC
    Wilson, JRH
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (12) : 3605 - 3609
  • [10] A new solid acid catalyst: the first phosphonate and phosphonic acid functionalised microporous polysilsesquioxanes
    Jurado-Gonzalez, M
    Ou, DL
    Ormsby, B
    Sullivan, AC
    Wilson, JRH
    [J]. CHEMICAL COMMUNICATIONS, 2001, (01) : 67 - 68