Critical energy for photopolymerization of ceramic suspensions in acrylate monomers

被引:86
作者
Tomeckova, Vladislava [1 ]
Halloran, John W. [1 ]
机构
[1] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA
关键词
Photopolymerization; SiO2; Al2O3; Suspensions; Rapid prototyping;
D O I
10.1016/j.jeurceramsoc.2010.08.003
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The critical energy dose E-c required for photopolymerization of silica and alumina suspensions in acrylate monomers was measured for a large series of suspensions, and contrasted with a model that based on the assumption that E-c is the dose necessary to exhaust the polymerization inhibitors. The major predictions of the model were in good agreement with the data: E-c is inversely proportional to photoinitiator concentration, directly proportional to inert dye concentration, and directly proportional to the concentration of inhibitors. (c) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3273 / 3282
页数:10
相关论文
共 11 条
[1]  
Doreau F, 2000, ADV ENG MATER, V2, P493, DOI 10.1002/1527-2648(200008)2:8<493::AID-ADEM493>3.3.CO
[2]  
2-3
[3]   Direct Inkjet Printing of dental Prostheses Made of Zirconia [J].
Ebert, J. ;
Oezkol, E. ;
Zeichner, A. ;
Uibel, K. ;
Weiss, Oe. ;
Koops, U. ;
Telle, R. ;
Fischer, H. .
JOURNAL OF DENTAL RESEARCH, 2009, 88 (07) :673-676
[4]   The persistent radical effect: A principle for selective radical reactions and living radical polymerizations [J].
Fischer, H .
CHEMICAL REVIEWS, 2001, 101 (12) :3581-3610
[5]   Absorption length for photon propagation in highly dense colloidal dispersions [J].
Garg, R ;
Prud'homme, RK ;
Aksay, IA ;
Liu, F ;
Alfano, RR .
JOURNAL OF MATERIALS RESEARCH, 1998, 13 (12) :3463-3467
[6]  
Jacobs P.F., 1992, Society of Manufacturing Engineers in cooperation with the Computer and Automated Systems Association of SME
[7]   Cure depth in photopolymerization: Experiments and theory [J].
Lee, JH ;
Prud'homme, RK ;
Aksay, IA .
JOURNAL OF MATERIALS RESEARCH, 2001, 16 (12) :3536-3544
[8]  
PROVIN C, 2002, IEEE T ELECT PACK MA, V25
[9]  
TOMECKOVA V, J EUR CERAM IN PRESS, DOI DOI 10.1016/J/JEURCERAMICSOC.2010.06.004
[10]   Predictive models for the photopolymerization of ceramic suspensions [J].
Tomeckova, Vladislava ;
Halloran, John W. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2010, 30 (14) :2833-2840