Valence delocalisation in a strongly coupled (Kc=1014) molecule-bridged cyanodiiron(III,II) species

被引：29
作者：
Ketterle, M
Fiedler, J
Kaim, W
机构：
[1] Univ Stuttgart, Inst Anorgan Chem, D-70550 Stuttgart, Germany
[2] Acad Sci Czech Republ, J Heyrovksy Inst Phys Chem, CR-18223 Prague, Czech Republic
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 16期
关键词：
D O I：
10.1039/a804279i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hybrid between the Prussian Blue and Creutz-Taube mixed valent species is presented in the form of the bmtz-bridged bis[tetracyanoiron(+2.5)] complex 1(3-) [bmtz = 3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine] which exhibits a very large comproportionation constant of 10(14) and a delocalised structure, according to UV-VIS-NIR-IR spectroelectrochemistry in acetonitrile solution.
引用
收藏
页码：1701 / 1702
页数：2
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