Electrochemically mediated ATRP of acrylamides in water

被引：97
作者：
Chmielarz, Pawel [1 ,2 ]
Park, Sangwoo [1 ]
Simakova, Antonina [1 ]
Matyjaszewski, Krzysztof [1 ]
机构：
[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
[2] Rzeszow Univ Technol, Dept Phys Chem, Fac Chem, PL-35959 Rzeszow, Poland
来源：
POLYMER | 2015年 / 60卷
基金：
美国国家科学基金会;
关键词：
ATRP; Aqueous media; Acrylamides; TRANSFER RADICAL POLYMERIZATION; ACTIVATION RATE CONSTANTS; ARGET ATRP; N-ISOPROPYLACRYLAMIDE; METHYL-METHACRYLATE; FUNCTIONAL MATERIALS; BLOCK-COPOLYMERS; THERMAL RESPONSE; SARA ATRP; ICAR ATRP;
D O I：
10.1016/j.polymer.2015.01.051
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Electrochemically mediated atom transfer radical polymerization (eATRP) of actylamide was investigated in aqueous media. The synthesis of poly(ethylene oxide)-block-poly(acrylamide) block copolymers via eATRP under potentiostatic conditions was carried out. Various polymerization parameters were examined, including temperature, monomer concentration, ligand structure, and degree of polymerization (DP). Under optimized reaction conditions, the DP of resulting copolymers increased linearly with monomer conversion and semilogarithmic kinetic plots were linear. Successful chain extension and formation of the block copolymers confirmed the living nature of the eATRP of acrylamides in aqueous media. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：302 / 307
页数：6
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