A route to single-crystalline ZnO films with low residual electron concentration

被引:11
作者
Liu, J. S. [1 ,2 ]
Shan, C. X. [1 ]
Wang, S. P. [1 ,2 ]
Sun, F. [1 ,2 ]
Yao, B. [1 ]
Shen, D. Z. [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Proc, Changchun 130033, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
关键词
X-ray diffraction; Molecular beam epitaxy; Zinc compounds; Semiconducting II-VI materials; EMISSION; DEFECTS; EPITAXY; GROWTH; GAN;
D O I
10.1016/j.jcrysgro.2010.07.006
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Single-crystalline ZnO films have been grown on a-plane sapphire in plasma assisted molecular beam epitaxy by introducing a high-temperature ZnO buffer layer. The residual electron concentration of the films can be lowered to 1.5 x 10(16) cm(-3), comparable with the best value ever reported for ZnO films grown on a rare and costly substrate of ScAlMgO4. A 3 x 3 reconstruction has been observed on the films grown in this route, which reveals that the films have very smooth surface. X-ray phi-scan spectrum of the films shows six peaks with 60 intervals, and two-dimensional X-ray diffraction datum indicates the single-crystalline nature of the films. Low temperature photoluminescence spectrum of the films shows a dominant free exciton emission and five phonon replicas, confirming the high quality of the films. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:2861 / 2864
页数:4
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