Palladium-catalyzed regioselective allylation of five-membered heteroarenes with allyltributylstannane

被引：31
|
作者：
Zhang, Sheng [1 ]
Yu, Xiaoqiang [1 ]
Feng, Xiujuan [1 ]
Yamamoto, Yoshinori [1 ,2 ]
Bao, Ming [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China
[2] Tohoku Univ, WPI AIMR, Sendai, Miyagi 9808577, Japan
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 18期
基金：
中国国家自然科学基金;
关键词：
C-H ALLYLATION; ALLYLIC ALCOHOLS; AROMATIC-COMPOUNDS; INDOLES; ALKYLATION; ARENES; ACIDS;
D O I：
10.1039/c4cc10373d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Palladium-catalyzed allylation reactions of 2-(chloromethyl)thiophenes, 2-(chloromethyl) furans, and N-protected 2-(chloromethyl)-1H-pyrroles with allyltributylstannane were described in this study. This type of allylation reaction regioselectively occurred on the heteroarene rings to produce allylated dearomatization products or allylated heteroarenes with satisfactory yields.
引用
收藏
页码：3842 / 3845
页数：4
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