Studies on (non) energetic compounds - Part 38. Kinetics of thermolysis of dichloroanilinium bromide salts

被引：4
|
作者：
Singh, G. [1 ]
Srivastava, P. [1 ]
Srivastava, J. [1 ]
机构：
[1] Gorakhpur Univ, Dept Chem, DDU, Gorakhpur 273009, Uttar Pradesh, India
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2007年 / 89卷 / 01期
关键词：
characterisation; dichloroanilinium bromide; isoconversional method; proton transfer; thermolysis;
D O I：
10.1007/s10973-004-6516-4
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Five salts of dichloroanilinium bromide (DCABr) were prepared and characterized by elemental and spectral studies. The thermal decomposition of DCABr was studied by using TG-DTG-DTA techniques and the results are discussed here. Kinetic parameters with the help of model fitting and isoconversional methods have been evaluated critically. A mechanism of decomposition has also been suggested.
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页码：181 / 189
页数：9
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