Study of thermodynamic properties of aqueous binary mixtures of glycine, L-alanine and β-alanine at low temperatures (T=275.15, 279.15, and 283.15) K

被引：20

作者：

Dhondge, Sudhakar S. ^{[1
]}

Paliwal, Rashmi L. ^{[2
]}

Bhave, Narayan S. ^{[2
]}

Pandhurnekar, Chandrashekhar P. ^{[3
]}

机构：

[1] SK Porwal Coll, PG Dept Chem, Kamptee 441002, India

[2] RTM Nagpur Univ, Dept Chem, Nagpur 440033, Maharashtra, India

[3] Shri Ramdeobaba Kamla Nehru Engn Coll, Nagpur 440013, Maharashtra, India

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2012年 / 45卷 / 01期

关键词：

Density; Speed of sound; Aqueous solutions of amino acids; Solute-solvent interactions; Temperature of maximum density; PARTIAL MOLAL EXPANSIBILITIES; WATER-PROTEIN INTERACTIONS; AMINO-ACIDS; MAXIMUM DENSITY; ADIABATIC COMPRESSIBILITIES; ORGANIC SOLUTES; HEAT-CAPACITIES; VOLUME; APPARENT; ELECTROLYTES;

D O I：

10.1016/j.jct.2011.09.016

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In the present communication, experimental values of density (rho) and speed of sound (u) of aqueous solutions of three amino acids, namely glycine, L-alanine and beta-alanine at different temperatures i.e. T = (275.15, 279.15, and 283.15) K are reported. From the experimental values, different derived parameters such as apparent molar volume of solute (phi(V)), isentropic compressibility of solution (beta(S)), apparent molar isentropic compressibility of solute (phi(KS)) have been calculated. The limiting values of apparent molar volume of solute (phi(0)(V)), apparent molar isentropic compressibility of solute (phi(0)(KS)) and apparent molar expansivity (phi(0)(E)) in the aqueous medium have also been obtained. The temperature coefficients of these limiting properties have also been computed. The results obtained were interpreted in terms of solute-solvent and solute-solute interactions, and structure making and structure breaking abilities of the solute in aqueous medium. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：114 / 121

页数：8

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