A Multifunctional Organic-Inorganic Hybrid Structure Based on MnIII-Porphyrin and Polyoxometalate as a Highly Effective Dye Scavenger and Heterogenous Catalyst

被引：415
作者：
Zou, Chao [2 ]
Zhang, Zhijuan [1 ]
Xu, Xuan [2 ]
Gong, Qihan [1 ]
Li, Jing [1 ]
Wu, Chuan-De [2 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA
[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 01期
关键词：
BUILDING-BLOCKS; FRAMEWORK; CHEMISTRY; EPOXIDATION; ADSORPTION; DIVERSITY; OXIDATION; POROSITY; DESIGN;
D O I：
10.1021/ja209196t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A two-step synthesis strategy has led to a unique layered polyoxometalate-Mn-III-metalloporphyrin-based hybrid material. The hybrid solid demonstrates remarkable capability for scavenging of dyes and for heterogeneous selective oxidation of alkylbenzenes with excellent product yields and 100% selectivity.
引用
收藏
页码：87 / 90
页数：4
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