Reactions of cationic isocyanide platinum(II) complexes with water (from hexafluoroacetone-hydrate): Carboxamido and isocyanato complexes

被引：6
|
作者：
Fehlhammer, Wolf Peter [1 ]
Bartel, Klaus [1 ]
Metzner, Robert [1 ]
Beck, Wolfgang [1 ]
机构：
[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 6-7期
关键词：
platinum; isocyanides; carboxamido complexes; isocyanato complexes;
D O I：
10.1002/zaac.200700540
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The isocyanide complexes [Pt(Cl)(C NR)(PPh3)(2)]+BF4- (R = CH2CO2Et, CH2Ph, C6H11, CH2SO2C6H4-p-Me) react with hexafluoroacetone-sesquihydrate, (F3C)(2)CO center dot 1,5 H2O, in the presence of triethylamine to give the carboxamido (carbamoyl) complexes [Pt(Cl){C(= O)NHR}(PPh3)(2)]. Under the same conditions the isocyanoamine complexes trans-[Pt(Cl)(C N-NR2)(PPh3)(2)]+BF4- (R = Et, Pr-i, 2R = CH(Me)(CH2)(3)CH(Me)) are transformed into the isocyanato complex trans-[Pt(Cl)(NCO)(PPh3)(2)].
引用
收藏
页码：1002 / 1004
页数：3
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