Application of Raman Spectroscopy to Ancient Materials: Models and Results from Archaeometric Analyses

被引:14
作者
Chiriu, Daniele [1 ]
Pisu, Francesca Assunta [1 ]
Ricci, Pier Carlo [1 ]
Carbonaro, Carlo Maria [1 ]
机构
[1] Univ Cagliari, Dept Phys, Cittadella Univ, I-09042 Monserrato, Italy
关键词
Raman spectroscopy; mathematical model; cultural heritage; CULTURAL-HERITAGE; IDENTIFICATION; CHEMOMETRICS; DEGRADATION; POTTERY; PAPER; SITE; INKS;
D O I
10.3390/ma13112456
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Numerous experimental techniques of analysis find applications in many branches of the archaeometry. Among them, Raman spectroscopy carved out a niche in the field of diagnostic and conservation of cultural heritage. The exceptional ability to predict and discover the structural properties of materials set for Raman spectroscopy, an exclusive role among the analytic techniques, is further boosted when it is coupled with mathematical or statistical models able to deepen the studied phenomena. In this work, we present a review of recent studies where pairing Raman spectroscopy and mathematical models allowed achieving important results in the case of potteries, porcelains, ancient and modern paper, ancient jewelry, and pigment degradation. The potentialities of this approach are evidenced and analyzed in detail.
引用
收藏
页数:17
相关论文
共 45 条
[1]  
Artioli Gilberto., 2010, Scientific Methods and Cultural Heritage: an introduction to the application of materials science to archaeometry and conservation science, DOI [10.1093/acprof:oso/9780199548262.001.0001, DOI 10.1093/ACPROF:OSO/9780199548262.001.0001]
[2]   Micro-Raman spectroscopy & THz time domain spectroscopic imaging of 'Pietra Dura' Marble inlay work resembling Taj Mahal architectural motifs [J].
Bandyopadhyay, Aparajita ;
Garg, Diksha ;
Sengupta, Amartya .
OPTICS FOR ARTS, ARCHITECTURE, AND ARCHAEOLOGY VII, 2019, 11058
[3]   Applications of Raman spectroscopy in art and archaeology [J].
Bersani, D. ;
Madariaga, J. M. .
JOURNAL OF RAMAN SPECTROSCOPY, 2012, 43 (11) :1523-1528
[4]   Raman microspectroscopy for Cultural Heritage studies [J].
Caggiani, Maria Cristina ;
Colomban, Philippe .
PHYSICAL SCIENCES REVIEWS, 2018, 3 (11)
[5]   The shining brightness of daylight fluorescent pigments: Raman and SERS study of a modern class of painting materials [J].
Campanella, Beatrice ;
Botti, Jole ;
Cavaleri, Tiziana ;
Cicogna, Francesca ;
Legnaioli, Stefano ;
Pagnotta, Stefano ;
Poggialini, Francesco ;
Poli, Tommaso ;
Scalarone, Dominique ;
Palleschi, Vincenzo .
MICROCHEMICAL JOURNAL, 2020, 152
[6]   A low-cost portable system for elemental mapping by XRF aiming in situ analyses [J].
Campos, P. H. O. V. ;
Appoloni, C. R. ;
Rizzutto, M. A. ;
Leite, A. R. ;
Assis, R. F. ;
Santos, H. C. ;
Silva, T. F. ;
Rodrigues, C. L. ;
Tabacniks, M. H. ;
Added, N. .
APPLIED RADIATION AND ISOTOPES, 2019, 152 :78-85
[7]   Beyond the surface: Raman micro-SORS for in depth non-destructive analysis of fresco layers [J].
Chiriu, D. ;
Desogus, G. ;
Pisu, F. A. ;
Fiorino, D. R. ;
Grillo, S. M. ;
Ricci, P. C. ;
Carbonaro, C. M. .
MICROCHEMICAL JOURNAL, 2020, 153
[8]   Raman characterization of XIV-XVI centuries Sardinian documents: Inks, papers and parchments [J].
Chiriu, D. ;
Ricci, P. C. ;
Cappellini, G. .
VIBRATIONAL SPECTROSCOPY, 2017, 92 :70-81
[9]   Ageing of ancient paper: A kinetic model of cellulose degradation from Raman spectra [J].
Chiriu, Daniele ;
Ricci, Pier Carlo ;
Cappellini, Giancarlo ;
Salis, Marcello ;
Loddo, Giorgia ;
Carbonaro, Carlo Maria .
JOURNAL OF RAMAN SPECTROSCOPY, 2018, 49 (11) :1802-1811
[10]   Portable NIR Raman microspectroscopy investigation on Early Bronze IV pottery (2500-1950 BCE) from Khirbat Iskandar, Jordan [J].
Chiriu, Daniele ;
Ricci, Pier Carlo ;
Scattini, Maddalena ;
Polcaro, Andrea ;
D'Andrea, Marta ;
Richard, Suzanne ;
Qader, Abdulqader Abdullah ;
Carbonaro, Carlo Maria .
VIBRATIONAL SPECTROSCOPY, 2018, 97 :8-15