Recent Advances in Enantioselective C-C Bond Formation via Organocobalt Species

被引：24

作者：

Yoshikai, Naohiko ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

SYNTHESIS-STUTTGART | 2019年 / 51卷 / 01期

关键词：

cobalt; asymmetric catalysis; C-C bond formation; hydrovinylation; C-H functionalization; cyclization; cross-coupling; HOMO DIELS-ALDER; PAUSON-KHAND REACTION; COBALT-CATALYZED 1,4-HYDROVINYLATION; CHIRAL PHOSPHINE-LIGANDS; ALPHA-BROMO ESTERS; 2+2+2 CYCLOADDITION; ASYMMETRIC HYDROVINYLATION; ALKYNES; KETONES; DELTACYCLENES;

D O I：

10.1055/s-0037-1610397

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This Short Review describes recent developments in cobalt-catalyzed enantioselective C-C bond-forming reactions. The article focuses on reactions that most likely involve chiral organocobalt species as crucial catalytic intermediates and their mechanistic aspects. 1 Introduction 2 Hydrovinylation 3 C-H Functionalization 4 Cycloaddition and Cyclization 5 Addition of Carbon Nucleophiles 6 Cross-Coupling 7 Conclusion

引用

页码：135 / 145

页数：11

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