Preparation and properties of weak acid ion-exchange membranes based on poly(vinylchloride)poly(methylmethacrylate-co-divinylbenzene) system

被引:0
|
作者
Alexandrova, I
Iordanov, G
机构
关键词
PVC/poly(MMA-co-DVB) system; carboxylic membranes preparation; properties;
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Weak acid ion-exchange membranes were obtained on the basis of PVC/poly(MMA-co-DVB) interpolymer-type systems. Carboxylic groups were introduced by acid hydrolysis of ester groups in poly(MMA-co-DVB) copolymer. It was found that suitable conditions for preparation of carboxylic membranes were: temperature of 353 K, 3 h reaction time, and acetic acid used. The best ion-exchange and electrochemical properties had membrane prepared from hydrolyzed PVC/poly(MMA-co-DVB) system with 5 wt % DVB. (C) 1996 John Wiley & Sons, Inc.
引用
收藏
页码:2285 / 2288
页数:4
相关论文
共 50 条
  • [21] Sulfonated poly(styrene-co-divinylbenzene) ion-exchange resins: acidities and catalytic activities in aqueous reactions
    Hart, M
    Fuller, G
    Brown, DR
    Dale, JA
    Plant, S
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 182 (01) : 439 - 445
  • [22] NON-EQUILIBRIUM PROPERTIES OF WEAK ION-EXCHANGE MEMBRANES
    STORMBERG, HP
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1977, 32 (12): : 1344 - 1352
  • [23] Improvements of lipase performance in high-viscosity system by immobilization onto a novel kind of poly(methylmethacrylate-co-divinylbenzene) encapsulated porous magnetic microsphere carrier
    Meng, Xiao
    Xu, Gang
    Zhou, Qin-Li
    Wu, Jian-Ping
    Yang, Li-Rong
    JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2013, 89 : 86 - 92
  • [24] Synthesis and characterization of magnetic porous Fe3O4/poly(methylmethacrylate-co-divinylbenzene) microspheres and their use in removal of Rhodamine B
    Shan, Jie
    Wang, Li
    Yu, Hao-jie
    Tai, Yu-lei
    Akram, Muhammad
    JOURNAL OF ZHEJIANG UNIVERSITY-SCIENCE A, 2015, 16 (08): : 669 - 679
  • [25] Preparation and properties of aminated poly(ethersulfone) ion-exchange membrane by UV irradiation method
    Choi, Kuk Jong
    Hwang, Eul Hwan
    Rhee, Young Woo
    Hwang, Taek Sung
    POLYMER-KOREA, 2008, 32 (01) : 70 - 76
  • [26] Characterization of poly(vinylchloride) (PVC) based cation exchange membranes prepared with ionic liquid
    Gizli, Nilay
    Cinarli, Sanem
    Demircioglu, Mustafa
    SEPARATION AND PURIFICATION TECHNOLOGY, 2012, 97 : 96 - 107
  • [27] PREPARATION OF PERFLUORINATED ION-EXCHANGE MEMBRANES AND THEIR APPLICATION IN ACID RECOVERY
    ELMIDAOUI, A
    CHERIF, AT
    BRUNEA, J
    DUCLERT, F
    COHEN, T
    GAVACH, C
    JOURNAL OF MEMBRANE SCIENCE, 1992, 67 (2-3) : 263 - 271
  • [28] Synthesis of Fe3O4@poly(methylmethacrylate-co-divinylbenzene) magnetic porous microspheres and their application in the separation of phenol from aqueous solutions
    Tai, Yulei
    Wang, Li
    Gao, Jingmin
    Amer, Wael A.
    Ding, Wenbing
    Yu, Haojie
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 360 (02) : 731 - 738
  • [29] FUNDAMENTAL PROPERTIES OF CROSS-LINKED POLY(METHACRYLIC ACID) ION-EXCHANGE RESINS
    HOWE, PG
    KITCHENER, JA
    JOURNAL OF THE CHEMICAL SOCIETY, 1955, : 2143 - 2151
  • [30] ELECTRIC AND ELECTROKINETIC TRANSPORT PROPERTIES OF HOMOGENEOUS WEAK ION-EXCHANGE MEMBRANES
    DEMISCH, HU
    PUSCH, W
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1979, 69 (02) : 247 - 270