Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster

被引：38

作者：

Chen, Kai-Jie ^{[1
]}

Perry, John J. ^{[1
]}

Scott, Hayley S. ^{[1
]}

Yang, Qing-Yuan ^{[1
]}

Zaworotko, Michael J. ^{[1
]}

机构：

[1] Univ Limerick, Dept Chem & Environm Sci, Limerick, Ireland

来源：

CHEMICAL SCIENCE | 2015年 / 6卷 / 08期

基金：

爱尔兰科学基金会;

关键词：

ORGANIC FRAMEWORKS MOFS; MOLECULAR TECTONICS; BUILDING-BLOCK; SINGLE-CRYSTAL; SURFACE-AREA; CO2; UPTAKE; DESIGN; LIGAND; CONSTRUCTION; ADSORPTION;

D O I：

10.1039/c5sc01515d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two isostructural metal-organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M7F122+ cluster that possesses 12 connection points but, because of double cross-linking by 3-connected Tripp ligands, it functions as a 6-connected supermolecular building block (SBB).

引用

页码：4784 / 4789

页数：6

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