Photochemical oxidation-ionic liquid extraction coupling technique in deep desulphurization of light oil

被引：48

作者：

Zhao, Dishun ^{[1
]}

Liu, Ran ^{[1
]}

Wang, Jianlong ^{[3
]}

Liu, Baoyou ^{[2
]}

机构：

[1] Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang Hebei 050018, Peoples R China

[2] Hebei Univ Sci & Technol, Coll Environm Sci & Engn, Shijiazhuang Hebei 050018, Peoples R China

[3] Tianjin Univ, Coll Chem Engn, Tianjin 300072, Peoples R China

来源：

ENERGY & FUELS | 2008年 / 22卷 / 02期

关键词：

D O I：

10.1021/ef700668h

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A photochemical oxidation and ionic liquid ([Bmim]PF6) extraction coupling technique was employed in deep desulphurization of light oil with the presence of photo oxidant H2O2. In this process, [Bmim]PF6 was utilized to be the extractant and photochemical reaction medium to promote the oxidation of dibenzothiophene (DBT). The deep oxidative desulfurization, 99.5% removal rate of DBT from n-octane and 90.6% sulfur removal rate of actual light oil, was achieved under mild conditions of room temperature and atmospheric pressure. The ionic liquid [Bmim]PF6 was recycled eight times with a slight decrease in desulfurization efficiency.

引用

页码：1100 / 1103

页数：4

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