Synthesis of bionic-macro/microporous MgO-modified TiO2 for enhanced CO2 photoreduction into hydrocarbon fuels

被引：33
|
作者：
Wang, Fang [1 ,2 ]
Zhou, Yong [1 ,3 ,4 ]
Li, Ping [3 ,4 ]
Kuai, Libang [3 ,4 ]
Zou, Zhigang [2 ,3 ]
机构：
[1] Nanjing Univ, Inst Acoust, Sch Phys, Key Lab Modern Acoust,MOE, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, Dept Mat Sci & Engn, Nanjing 210093, Jiangsu, Peoples R China
[3] Nanjing Univ, ERERC, Nanjing 210093, Jiangsu, Peoples R China
[4] Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Natl Lab Solid State Microstruct, Jiangsu Key Lab NanoTechnol, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF CATALYSIS | 2016年 / 37卷 / 06期
基金：
中国国家自然科学基金;
关键词：
Magnesium oxide; Titanium dioxide; Carbon dioxide photoreduction; Carbon dioxide activiation; Bionic-porous structure; Biotemplate; HIGH-YIELD SYNTHESIS; PHOTOCATALYTIC REDUCTION; CARBON-DIOXIDE; ROOM-TEMPERATURE; NANOPARTICLES; NANORIBBONS; ULTRATHIN; HYDROGENATION; NANOSHEETS; ROUTE;
D O I：
10.1016/S1872-2067(15)61111-1
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The stems of water convolvulus were employed as biotemplates for the replication of their optimized 3D hierarchical architecture to synthesize porous MgO-modified TiO2. The photocatalytic reduction of CO2 with H2O vapor into hydrocarbon fuel was studied with these MgO-TiO2 nanostructures as the photocatalysts with the benefits of improved CO2 adsorption and activation through incorporated MgO. Various factors involving CO2 adsorption capacity, migration of charge carriers to the surface, and the number of activity sites, which depend on the amount of added MgO, determine the photocatalytic conversion efficiency. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：863 / 868
页数：6
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